HIGHER-ORDER VARIATIONS OF L-TYPE DOUBLING CONSTANTS AND CENTRIFUGAL DISTORTION CONSTANTS FOR HCN AND OCS

被引：39

作者：

NAKAGAWA, T

MORINO, Y

机构：

[1] Department of Chemistry, Faculty of Science, The University of Tokyo, Hongo, Bunkyo-ku, Tokyo

来源：

JOURNAL OF MOLECULAR SPECTROSCOPY | 1969年 / 31卷 / 02期

关键词：

D O I：

10.1016/0022-2852(69)90355-5

中图分类号：

O64 [物理化学（理论化学）、化学物理学]; O56 [分子物理学、原子物理学];

学科分类号：

070203 ; 070304 ; 081704 ; 1406 ;

摘要：

The v- and J-dependences of the ℓ-type doubling constant qv and of the centrifugal distortion constant Dv for linear XYZ molecules have been formulated by means of Amat and Nielsen's fourth-order theory of vibration-rotation interactions. Practical applications of the formulas have been carried out for HCN, OCS and their isotopic species by using anharmonic potential functions involving cubic and quartic terms. © 1969.

引用

页码：208 / &

共 36 条

[1]

AMAT G, 1957, J CHEM PHYS, V27, P845, DOI 10.1063/1.1743863

[2] HIGHER ORDER ROTATION-VIBRATION ENERGIES OF POLYATOMIC MOLECULES .4. [J].