SELF-ASSEMBLY OF MOLECULAR-SIZED BOXES

被引：128
|
作者：
HUNTER, CA
机构：
[1] Department of Chemistry, University of Sheffield, Gb-Sheffield
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1995年 / 34卷 / 10期
关键词：
MOLECULAR RECOGNITION; NONCOVALENT INTERACTIONS; SELF-ASSEMBLY;
D O I：
10.1002/anie.199510791
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A simple recipe for tailored cavities for the recognition of neutral organic guests: just mix difunctional chelate ligands with metal ions having a preferred coordination geometry. Boxes, cylinders, or tetrahedra form in high yields by self‐assembly. Of course it's not quite this easy, but the studies discussed here indicate that this strategy for the construction of macrocyclic hosts has a bright future. Copyright © 1995 by VCH Verlagsgesellschaft mbH, Germany
引用
收藏
页码：1079 / 1081
页数：3
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