THE INTERACTION OF COORDINATIONALLY UNSATURATED 2,9-DIMETHYLPHENANTHROLINE COBALT COMPLEX WITH ADENINE-NUCLEOTIDES

被引：2
|
作者：
KISELEVA, LL
NOVODAROVA, GN
MIRONOV, EA
KRAINOVA, NY
VOLPIN, ME
机构：
[1] A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Moscow, 117813
来源：
RUSSIAN CHEMICAL BULLETIN | 1994年 / 43卷 / 04期
关键词：
2,9-DIMETHYLPHENANTHROLINE; COBALT COMPLEX; MITOCHONDRIA;
D O I：
10.1007/BF00699850
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The study of complex formation between adenosine triphosphate (ATP) or adenosine diphosphate (ADP) and coordinationally unsaturated cobalt complex with 2,9-dimethyl-o-phenanthroline (L) showed the possibility of formation of relatively stable mixed ligand complex CoL.ATP (log beta = 4.45). The latter may be formed under the oxidative phosphorylation conditions in mitochondria. The presence of ATP in the complex provides the specific inhibition of the ATPase active center.
引用
收藏
页码：696 / 701
页数：6
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