4-Hydroxy-3-methoxybenzaldehyde thiosemicarbazone

被引：6

作者：

de Oliveira, Adriano Bof ^{[1
]}

Santos Feitos, Barbara Regina ^{[1
]}

Nather, Christian ^{[2
]}

Jess, Inke ^{[2
]}

机构：

[1] Univ Fed Sergipe, Dept Quim, Av Marechal Rondon S-N Campus, BR-49100000 Sao Cristovao, SE, Brazil

[2] Christian Albrechts Univ Kiel, Inst Anorgan Chem, D-24118 Kiel, Germany

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2013年 / 69卷

关键词：

D O I：

10.1107/S1600536813032303

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

In the title compound, C9H11N3S, there is an intramolecular O-H center dot center dot center dot O hydrogen bond involving the OH group and the adjacent methoxy O atom. The molecule is essentially planar, with the maximum deviation from the mean plane of the nonH atoms being 0.1127 (14) angstrom for the methyl C atom. In the crystal, molecules are connected via centrosymmetric pairs of N-H center dot center dot center dot S and O-H center dot center dot center dot O hydrogen bonds into a twodimensional network parallel to (10 (3) over bar).

引用

页码：O1861 / +

页数：7

共 7 条

[1]

Brandenburg K., 2006, DIAMOND

[2] Thiosemicarbazide as reagent on aldehyde and ketons. [J].

Freund, M ;

Schander, A .

BERICHTE DER DEUTSCHEN CHEMISCHEN GESELLSCHAFT, 1902, 35 :2602-2606

[3] 2-Hydroxy-4-methoxybenzaldehyde thiosemicarbazone [J].

Hao, Yu-Mei .

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2010, 66 :O2211-U1436

[4] Synthesis and in vitro antimalarial and antitubercular activity of gold(III) complexes containing thiosemicarbazone ligands [J].

Khanye, Setshaba D. ;

Wan, Baojie ;

Franzblau, Scott G. ;

Gut, Jiri ;

Rosenthal, Philip J. ;

Smith, Gregory S. ;

Chibale, Kelly .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2011, 696 (21) :3392-3396

[5] A short history of SHELX [J].

Sheldrick, George M. .

ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES, 2008, 64 :112-122

[6]

Stoe & Cie, 2008, X AREA X RED32 X SHA

[7] publCIF: software for editing, validating and formatting crystallographic information files [J].

Westrip, Simon P. .

JOURNAL OF APPLIED CRYSTALLOGRAPHY, 2010, 43 :920-925

← 1 →