THE FIRST MIXED-METAL BOROLE CLUSTER - STABILIZATION OF FORMALLY 14E PD CENTERS IN THE RE2PD2 ELECTRON-DEFICIENT [([(ETA(5)-C(4)H(4)BPH)(CO)(3)RE]PD)(2)] CLUSTER

被引：23

作者：

BRAUNSTEIN, P ^{[1
]}

ENGLERT, U ^{[1
]}

HERBERICH, GE ^{[1
]}

NEUSCHUTZ, M ^{[1
]}

机构：

[1] RHEIN WESTFAL TH AACHEN,INST ANORGAN CHEM,D-52074 AACHEN,GERMANY

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1995年 / 34卷 / 09期

关键词：

BOROLE LIGANDS; ELECTRON-DEFICIENT COMPOUNDS; PALLADIUM COMPOUNDS; RHENIUM COMPOUNDS;

D O I：

10.1002/anie.199510101

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Borole and cluster chemistry are combined for the first time. The result is the title compound (shown right), a novel, intriguing Re2Pd2 cluster with 54 valence electrons. X‐ray structure analysis of this compound, which forms deep blue‐green crystals, showed that the Re2Pd2 unit is planar. (Figure Presented.) Copyright © 1995 by VCH Verlagsgesellschaft mbH, Germany

引用

页码：1010 / 1012

页数：3

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