FACILE TRANSFER OF TERTIARY ALKYL-GROUPS FROM BORON TO CARBON IN BASE-INDUCED REACTION OF ALPHA,ALPHA-DICHLOROMETHYL METHYL-ETHER WITH ORGANOBORANES CONTAINING TERTIARY ALKYL-GROUPS - NOVEL ROUTE TO HIGHLY HINDERED TRIALKYLCARBINOLS INVOLVING EXCEPTIONALLY MILD CONDITIONS

被引：35

作者：

BROWN, HC ^{[1
]}

KATZ, JJ ^{[1
]}

CARLSON, BA ^{[1
]}

机构：

[1] PURDUE UNIV,RICHARD B WETHERILL LAB,W LAFAYETTE,IN 47907

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1973年 / 38卷 / 22期

关键词：

D O I：

10.1021/jo00962a041

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

引用

页码：3968 / 3970

页数：3

共 9 条

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[2] CARBONYLATION OF THEXYLDIALKYLBORANES . A NEW GENERAL SYNTHESIS OF KETONES [J].

BROWN, HC ;

NEGISHI, E .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1967, 89 (20) :5285-&

[3] CARBONYLATION OF ORGANOBORANES FROM CYCLIC HYDROBORATION OF DIENES WITH THEXYLBORANE . A SIMPLE PROCEDURE FOR CONVERSION OF DIENES INTO CYCLIC KETONES [J].

BROWN, HC ;

NEGISHI, E .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1967, 89 (21) :5477-&

[4] ORGANOBORANES .16. TRIETHYLMETHANOL ESTERS OF TERT-ALKYLFLUOROBORONIC ACIDS - NEW CLASS OF ORGANOBORANE INTERMEDIATE REMARKABLY STABLE TO OXIDATION AND ALKALINE-HYDROLYSIS [J].

BROWN, HC ;

CARLSON, BA .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1973, 54 (JUN16) :61-68

[5] FAST BASE-INDUCED REACTION OF ALPHA,ALPHA-DICHLOROMETHYL METHYL-ETHER WITH ORGANOBORANES - NEW GENERAL ROUTE FROM ORGANOBORANES TO CORRESPONDING CARBON STRUCTURES [J].

BROWN, HC ;

CARLSON, BA .

JOURNAL OF ORGANIC CHEMISTRY, 1973, 38 (13) :2422-2424

[6]

BROWN HC, 1972, SYNTH-INT J METHODS, P304

[7]

NEGISHI E, 1972, SYNTH-INT J METHODS, P196

[8]

PELTER A, 1973, CHEM IND-LONDON, P206

[9]

PELTER A, 1970, CHEM COMMUN, P1529

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