A QUANTITATIVE APPROACH TO DESCRIBE THE OVERALL MOTION OF MONOSACCHARIDES IN SOLUTION - A C-13 NMR RELAXATION STUDY OF 1,6-ANHYDRO-BETA-D-GLUCOPYRANOSE IN DIMETHYL-SULFOXIDE

被引:16
作者
DAIS, P
机构
[1] Department of Chemistry, University of Crete, 71409 Iraklion, Crete
关键词
C-13; NMR; 1,6-ANHYDRO-BETA-D-GLUCOPYRANOSE IN ME(2)SO;
D O I
10.1016/0008-6215(94)87001-2
中图分类号
Q5 [生物化学]; Q7 [分子生物学];
学科分类号
071010 ; 081704 ;
摘要
Quantitative aspects describing the dynamics of monosaccharides in solution by employing C-13 NMR relaxation are reported in this work. This method has been applied to analyze the variable temperature C-13 spin-lattice relaxation times of 1,6-anhydro-beta-D-grucopyranose, which appears to tumble anisotropically in dimethyl sulfoxide solution.
引用
收藏
页码:13 / 24
页数:12
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