SYNTHESIS AND CRYSTAL-STRUCTURE OF THE DIETHYLAMINOGALLANE DIMER, [H2GAN(CH2CH3)2]2

被引：0
|
作者：
LORBERTH, J
DORN, R
MASSA, W
WOCADLO, S
机构：
来源：
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES | 1993年 / 48卷 / 02期
关键词：
DIETHYLAMINE-GALLANE; DIETHYLAMIDO-GALLANE; SYNTHESIS; CRYSTAL STRUCTURE;
D O I：
暂无
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The title compound was prepared by reacting gallane etherate H3Ga.OEt2 at -40-degrees-C in Et2O with diethylamine upon warming to room temperature for several hours. It forms white crystals from ether solution which were identified by X-ray structure determination. Space group C2/c, Z = 4; 930 observed unique reflections, R/wR = 0.0482/0.0450. Lattice dimensions at 193 K: a = 1292.9(3), b = 721.1(2), c = 1443.1(2) pm; beta = 92.81(2)degrees. The structure reveals a centrosymmetric dimeric molecule with a planar square (GaN)2 fourmembered ring: average distance Ga-N 201.7 pm, Ga...Ga 284.5(2) pm.
引用
收藏
页码：224 / 226
页数：3
相关论文
共 50 条
  • [31] Solvothermal synthesis and crystal structure of [H2N(CH2)2NH3]{CO[H2N(CH2)2NH2]3}[SbSe4]
    Ming-Lai, F
    Chen, WT
    Cai, LZ
    Liu, B
    Guo, GC
    Huang, JS
    CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2004, 23 (07) : 731 - 734
  • [32] Synthesis and crystal structure of [Y(C5Me4SiMe3){μ-O(CH2)3CH3}{N(SiHMe2)2}]2
    Luo Yunjie
    Feng Xiaoying
    JOURNAL OF RARE EARTHS, 2011, 29 (01) : 24 - 27
  • [33] Synthesis and characterization of a series of aminogallanes, [Me2GaR]2 -: The crystal structures of [Me2GaN(CH2Ph)2]2 and [Me2GaN(CH2CH2)2NMe]2
    Schauer, SJ
    Lake, CH
    Watkins, CL
    Krannich, LK
    Powell, DH
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1997, 549 (1-2) : 31 - 37
  • [34] Synthesis, characterization and crystal structure of binuclear nickel (II) complex [Ni2(bbimp) (CH3CH2OH)2Cl2]Cl • 4H2O
    Yang, P
    Zhou, CQ
    Li, SE
    Zhu, ML
    CHINESE JOURNAL OF INORGANIC CHEMISTRY, 2003, 19 (04) : 415 - 418
  • [35] Synthesis, spectroscopic properties and crystal structures of SnBr2[S2CN(CH2CH2)2O]2, (4-F-C6H4CH2)2Sn(Cl)S2CN(CH2CH2)2O and (2-F-C6H4CH2)3SnS2CN(CH2CH2)2O
    Yin, HD
    Wang, C
    Hong, M
    Wang, D
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2004, 689 (07) : 1277 - 1283
  • [36] Solvothermal Synthesis and Crystal Structure of [H2N（CH2）2NH3]{Co[H2N（CH2）2NH2]3}[SbSe4]
    FU Ming-Lai a
    结构化学, 2004, (07) : 731 - 734
  • [37] Synthesis and crystal structure of [C5H4C(CH3)(C2H7)CH2CH = CH2]Gd(OH)Cl•2MgCl2•4THF
    Lin, J
    Wang, ZY
    Wang, HG
    CHINESE JOURNAL OF ORGANIC CHEMISTRY, 2000, 20 (03) : 377 - 381
  • [38] Synthesis and crystal structure of a palladium dimer containing ferrocenyldiphenylphosphine, trans-[Pd(μ-Cl)(CH3)(PPh2Fc)]2
    Stefanus Otto
    Journal of Chemical Crystallography, 2001, 31 : 185 - 190
  • [39] Synthesis, NMR spectra and structure of [(CH3)2Ga{μ-P(H)Si(CH3)3}2Ga(CH3)2{μ-P(Si(CH3)3)2}Ga(CH3)2]
    Schaller, A
    Hausen, HD
    Weidlein, J
    Fischer, P
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2000, 626 (03): : 616 - 618
  • [40] Crystal and molecular structure of [(C6H5)(2)P(=O)(CH2CH2N(CH3)(3))(+)][I-]
    Churchill, MR
    See, RF
    Rominger, RL
    Atwood, JD
    JOURNAL OF CHEMICAL CRYSTALLOGRAPHY, 1996, 26 (11) : 747 - 752
12345