SYNTHESIS AND CRYSTAL-STRUCTURE OF THE DIETHYLAMINOGALLANE DIMER, [H2GAN(CH2CH3)2]2

被引：0

作者：

LORBERTH, J

DORN, R

MASSA, W

WOCADLO, S

机构：

来源：

ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES | 1993年 / 48卷 / 02期

关键词：

DIETHYLAMINE-GALLANE; DIETHYLAMIDO-GALLANE; SYNTHESIS; CRYSTAL STRUCTURE;

D O I：

暂无

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The title compound was prepared by reacting gallane etherate H3Ga.OEt2 at -40-degrees-C in Et2O with diethylamine upon warming to room temperature for several hours. It forms white crystals from ether solution which were identified by X-ray structure determination. Space group C2/c, Z = 4; 930 observed unique reflections, R/wR = 0.0482/0.0450. Lattice dimensions at 193 K: a = 1292.9(3), b = 721.1(2), c = 1443.1(2) pm; beta = 92.81(2)degrees. The structure reveals a centrosymmetric dimeric molecule with a planar square (GaN)2 fourmembered ring: average distance Ga-N 201.7 pm, Ga...Ga 284.5(2) pm.

引用

页码：224 / 226

页数：3

共 50 条

[21] Synthesis and Crystal Structure of the Copper Complex {[Cu（CH3COO）2（bbtz）]（H2O）2}n
ZHANG Yong ZHANG Yu-Mei LIU Xun-Gao LI Bao-Long② (Key Laboratory of Organic Synthesis of Jiangsu Province
结构化学, 2005, (10) : 1129 - 1132
[22] FORMATION AND CRYSTAL-STRUCTURE OF ETHYLENEDIAMMONIUM HYDRIDOTRIOXOPHOSPHATE(2-) [H3NCH2CH2NH3][PHO3]
HONLE, W
WALZ, L
VONSCHNERING, HG
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 1990, 45 (09): : 1251 - 1254
[23] Synthesis and Characterization of （CH3CH2CH2CH2NH3）2SnBr6
ZHANG Zhang-Jing GUO Guo-Cong② CAI Li-Zhen ZHOU Guo-Wei LIU Bing CHEN Wen-Tong WU A-Qing FU Ming-Lai HUANG Jin-Shun (State Key Laboratory of Structural Chemistry
Chinese Journal of Structural Chemistry, 2005, (03) : 359 - 363
[24] Hydrothermal synthesis and crystal structure of [In2(HPO3)4] •(NH3CH2CH2NH3)
Liu Cheng-Zhan
Zhu Guang-Shan
Fang Qiang-Rong
Xue Ming
Sun Fu-Xing
Qiu Shi-Lun
CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE, 2007, 28 (09): : 1637 - 1639
[25] Synthesis and crystal structure of the copper complex {[Cu(CH3COO)2(bbtz)](H2O)2}n
Zhang, Y
Zhang, YM
Liu, XG
Li, BL
CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2005, 24 (10) : 1129 - 1132
[26] Synthesis and characterization of (CH3CH2CH2CH2NH3)2SnBr6
Zhang, ZJ
Guo, GC
Cai, LZ
Zhou, GW
Liu, B
Chen, WT
Wu, AQ
Fu, ML
Huang, JS
CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2005, 24 (03) : 359 - 363
[27] Synthesis, crystal structure, EPR of (NH2CH2CH2NH3)4[WVO2(OC6H4O)2]2(NH3CH2CH2NH3)•H2O and comparison with its isomorphic complexes
Lu, XM
Song, FG
Wang, B
Li, L
CHINESE JOURNAL OF INORGANIC CHEMISTRY, 2005, 21 (11) : 1687 - 1690
[28] SYNTHESIS AND CRYSTAL-STRUCTURE OF [TECL2(NPME(3))(2)](2)
FOLKERTS, H
DEHNICKE, K
MAGULL, J
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 1995, 50 (04): : 573 - 576
[29] Synthesis and crystal structure of complex [Ni(IDB)2]2•(SO4)2•3CH3CH2OH•CH3OH•5H2O and its fluorescence spectrum
Chen Yan-Guo
He Zhi-Ke
Zhang Lan
Chen Qiong
Lu Jiang-Lin
Deng Zhen-Li
Chen Ling
Wang Wei-Dong
ACTA CHIMICA SINICA, 2008, 66 (14) : 1651 - 1657
[30] Synthesis and crystal structure of [Y(C5Me4SiMe3){μ-O(CH2)3CH3}{N(SiHMe2)2}]2
罗云杰
冯晓莹
Journal of Rare Earths, 2011, 29 (01) : 24 - 27

← 1 2 3 4 5 →