SYNTHESIS OF BINUCLEAR PLATINUM METAL N4O2-COMPARTMENTAL COMPLEXES - THE STRUCTURES OF THE PROTONATED METAL-FREE MACROCYCLE [LH4](PF6)2.MENO2 AND OF [PD2(L)](BF4)2.2MENO2

被引：39

作者：

ATKINS, AJ ^{[1
]}

BLAKE, AJ ^{[1
]}

SCHRODER, M ^{[1
]}

机构：

[1] UNIV EDINBURGH,DEPT CHEM,W MAINS RD,EDINBURGH EH9 3JJ,MIDLOTHIAN,SCOTLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1993年 / 04期

关键词：

D O I：

10.1039/c39930000353

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reaction of [LH4](PF6)2, formed by condensation of 1,3-diaminopropane and 2,6-diformyl-4-methylphenol in the presence of HBr followed by addition of NH4PF6, with platinum metal salts in the presence of base affords [M2(L)]2+ (M = Pd, Pt) and [M2Cl4(L)] (M = Rh); the structure of [LH4](PF6)2.MeNO2 shows a folded conformation incorporating both inter- and intra-molecular pi-pi interactions between phenyl rings; in contrast, the structure of [Pd2(L)](BF4)2.2MeNO2 shows the binucleating macrocycle to be planar with intermolecular pi-ring stacking.

引用

页码：353 / 355

页数：3

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