THE EFFECT OF FIXED-BED REACTOR CONFIGURATION ON THE OXIDATIVE COUPLING OF METHANE OVER A LI/PB/CA CATALYST

被引：16

作者：

SMITH, KJ

PAINTER, TM

GALUSZKA, J

机构：

[1] ALBERTA RES COUNCIL,DEPT COAL & HYDROCARBON PROC,DEVON T0C 1E0,ALBERTA,CANADA

[2] CANADA CTR MINERAL & ENERGY TECHNOL,ENERGY RES LABS,OTTAWA K1A OG1,ONTARIO,CANADA

来源：

CATALYSIS LETTERS | 1991年 / 11卷 / 3-6期

关键词：

METHANE; OXIDATIVE COUPLING; CATALYST; REACTOR CONFIGURATION;

D O I：

10.1007/BF00764321

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Introduction of additional O2 at the midpoint of the catalyst bed of a methane oxidative coupling, fixed bed reactor, increases the C2 STY more than the COx STY over a Li/Pb/Ca catalyst. This observation is not only a consequence of kinetics but may also be attributed to increased methyl radical generation on the O2 replenished catalyst surface.

引用

页码：301 / 307

页数：7

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