COLD-VAPOR MERCURY ATOMIC-ABSORPTION SPECTROMETRY - HCL AS THE CAUSE OF THE DOUBLE PEAK PHENOMENON

被引：4

作者：

DANIELS, RS ^{[1
]}

WIGFIELD, DC ^{[1
]}

机构：

[1] CARLETON UNIV,DEPT CHEM,OTTAWA CARLETON CHEM INST,OTTAWA K1S 5B6,ONTARIO,CANADA

来源：

JOURNAL OF ANALYTICAL TOXICOLOGY | 1993年 / 17卷 / 04期

基金：

加拿大自然科学与工程研究理事会;

关键词：

D O I：

10.1093/jat/17.4.196

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

An investigation has been made on the intermittent second peak that occurs in cold-vapor mercury atomic absorption spectrometry. Evidence that this peak is due to hydrogen chloride gas is presented. Analytical determination of mercury should therefore not include this peak, and a means to suppress or eliminate it, using glass wool adsorption between the reaction vessel and the spectrometer, is suggested. © 1993 Oxford University Press.

引用

页码：196 / 198

页数：3

共 6 条

[1] COLD-VAPOR MERCURY ATOMIC-ABSORPTION SPECTROMETRY .2. ACIDIC VERSUS ALKALINE REDUCTION [J].

DANIELS, RS ;

WIGFIELD, DC .

SCIENCE OF THE TOTAL ENVIRONMENT, 1989, 89 (03) :325-329

[2] COLD-VAPOR MERCURY ATOMIC-ABSORPTION SPECTROMETRY .1. REAGENT VOLUME OPTIMIZATION [J].

DANIELS, RS ;

WIGFIELD, DC .

SCIENCE OF THE TOTAL ENVIRONMENT, 1989, 89 (03) :319-323

[3] IMPROVED COLD-VAPOR ATOMIC-ABSORPTION TECHNIQUE FOR THE MICRO-DETERMINATION OF TOTAL AND INORGANIC MERCURY IN BIOLOGICAL SAMPLES [J].

FARANT, JP ;

BRISSETTE, D ;

MONCION, L ;

BIGRAS, L ;

CHARTRAND, A .

JOURNAL OF ANALYTICAL TOXICOLOGY, 1981, 5 (01) :47-51

[4]

STURGEON RE, 1979, THESIS CARLETON U OT, P141

[5] ELECTRONIC SPECTRA AND STRUCTURE OF HYDROGEN HALIDES - B3PII AND C1PI STATES OF HCL AND DCL [J].

TILFORD, SG ;

GINTER, ML ;

VANDERSLICE, JT .

JOURNAL OF MOLECULAR SPECTROSCOPY, 1970, 33 (03) :505-+

[6] THE OBSERVATION OF UNUSUALLY LARGE BLANK VALUES IN THE COLD-VAPOR ATOMIC-ABSORPTION ANALYSIS FOR TOTAL MERCURY [J].

WIGFIELD, DC ;

DANIELS, RS .

JOURNAL OF ANALYTICAL TOXICOLOGY, 1988, 12 (02) :94-97

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