Hexaaquabis[3,5-bis(hydroxyimino)-1-methyl-2,4,6-trioxocyclohexanido-kappa N-2(3),O-4]barium tetrahydrate

被引：0
|
作者：
Nguyen Dinh Do [1 ]
Kovalchukova, Olga [2 ]
Stash, Adam [3 ]
Strashnova, Svetlana [2 ]
机构：
[1] Hanoi Univ Min & Geol, Hanoi, Vietnam
[2] Peoples Friendship Univ Russia, Moscow 117198, Russia
[3] Karpov Inst Phys Chem, Moscow 105064, Russia
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2013年 / 69卷
基金：
俄罗斯基础研究基金会;
关键词：
D O I：
10.1107/S1600536813027761
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
In the title compound, [Ba(C7H5N2O5)(2)(H2O)(6)]center dot 4H(2)O, the Ba2+ cation lies on a twofold rotation axis and is ten-coordinated by two 3,5-bis(hydroxyimino)-1-methyl-2,4,6-trioxocyclohexanide oxo O atoms [Ba-O = 2.8715 (17) angstrom], two hydroxyimino N atoms [Ba-N = 3.036 (2) angstrom], and six water molecules [Ba-O = 2.847 ( 2), 2.848 (2), and 2.880 (2) angstrom]. The 3,5-bis(hydroxyimino)-1-methyl-2,4,6-trioxocyclohexanide monoanions act in a bidentate chelating manner, coordinating through an N atom of the non-deprotonated hydroxyimino group and an O atom of the neighboring oxo group. Two lattice water molecules are located in the cavities of the framework and are involved in hydrogen bonding to O atoms of one of the coordinating water molecules and the O atom of a keto group of the ligand. As a result, a three-dimensional network is formed.
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页码：M602 / +
页数：9
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