Time-domain calculation of chemical exchange effects in the NMR spectra of rotating solids

被引：27

作者：

Duer, M. J. ^{[1
]}

Levitt, M. H. ^{[2
]}

机构：

[1] Univ Cambridge, Dept Chem, Cambridge CB2 1EW, England

[2] Univ Stockholm, Arrhenius Lab, S-10691 Stockholm, Sweden

来源：

SOLID STATE NUCLEAR MAGNETIC RESONANCE | 1992年 / 1卷 / 04期

关键词：

solid-state NMR; chemical exchange; magic-angle spinning; simulation; spinning sidebands;

D O I：

10.1016/S0926-2040(10)80006-2

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A simple method is described for the calculation of magic-angle-spinning (MAS) spectra of solids in the presence of chemical exchange. The method converges quickly, allowing rapid calculation of the spectra, Calculated spectra are given for molecular motion involving 2 and 6 sites.

引用

页码：211 / 215

页数：5

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