PHOTODISSOCIATION OF CHARGE-TRANSFER COMPLEXES BASED ON AROMATIC-AMINES AND BROMINE-CONTAINING ELECTRON-ACCEPTORS

被引：0

作者：

GRISHINA, AD ^{[1
]}

TEDORADZE, MG ^{[1
]}

VANNIKOV, AV ^{[1
]}

机构：

[1] AN FRUMKIN ELECTROCHEM INST,MOSCOW 117071,USSR

来源：

MENDELEEV COMMUNICATIONS | 1992年 / 02期

关键词：

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Ionic photodissociation of Am.HBMS donor-acceptor complexes leads to the formation of a primary coloured product that is a diphenylmethane dye and acid H+[S(O)2CBr3] if Am is diphenylamine, or N,N-diphenylphenylmethyleneiminium bromide and acid H+[CBr2=S(O)2-CBr3]- if Am is diphenylbenzylamine [hexabromodimethylsulfone (HBMS) is the electron acceptor]; the structure of the amine determines the difference in the coloured products.

引用

页码：44 / 45

页数：2

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