REACTIONS OF CHIRAL 2-PARA-TOLYSULFINYLCYCLOALKANONES WITH ALME3

被引：18

作者：

BUENO, AB

CARRENO, MC

FISCHER, J

RUANO, JLG

PENA, B

PENAS, L

RUBIO, A

机构：

[1] UNIV AUTONOMA MADRID, DEPT QUIM, CANTOBLANCO, E-28049 MADRID, SPAIN

[2] UNIV STRASBOURG 1, CRISTALLOCHIM LAB, UA 424, F-67070 STRASBOURG, FRANCE

来源：

TETRAHEDRON LETTERS | 1991年 / 32卷 / 27期

关键词：

D O I：

10.1016/S0040-4039(00)79719-X

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The reactions of (S2,Rs) and (R2,Rs)-2-p-tolylsulfinylcyclohexanones with AlMe3/ZnCl2 only yield the cyclohexylmethylcarbinols with R configuration at hydroxylic carbon. The (R1,S2,Rs)-1-methyl-2-p-tolylsulfinylcyclopentanol was the only compound obtained in the reaction of Me3Al with both epimeric 2-p-tolylsulfinylcyclopentanones. The d.e. of both reactions are higher than 96%.

引用

页码：3191 / 3194

页数：4

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