HCN DIMERS - PHOTOELECTRON-SPECTRUM OF IMINOACETONITRILE

被引：17

作者：

EVANS, RA

LACOMBE, SM

SIMON, MJ

PFISTERGUILLOUZO, G

WENTRUP, C

机构：

[1] UNIV QUEENSLAND,DEPT CHEM,BRISBANE,QLD 4072,AUSTRALIA

[2] UNIV PAU,PHYSICOCHIM MOLEC LAB,CNRS,UA 474,F-64000 PAU,FRANCE

来源：

JOURNAL OF PHYSICAL CHEMISTRY | 1992年 / 96卷 / 12期

关键词：

D O I：

10.1021/j100191a015

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The photoelectron spectrum of iminoacetonitrile (HN=CHCN), obtained by gentle pyrolysis of the sodium salt of 1-cyanoformamide tosylhydrazone at 200-degrees-C, is reported. The first (vertical) ionization potentials are 11.60, 12.34, 13.09, 13.84, and 14.51 eV. These are compared with those of N-cyanomethanimine (CH2=N-CN).

引用

页码：4801 / 4804

页数：4