HCN DIMERS - PHOTOELECTRON-SPECTRUM OF IMINOACETONITRILE

被引：17
|
作者：
EVANS, RA
LACOMBE, SM
SIMON, MJ
PFISTERGUILLOUZO, G
WENTRUP, C
机构：
[1] UNIV QUEENSLAND,DEPT CHEM,BRISBANE,QLD 4072,AUSTRALIA
[2] UNIV PAU,PHYSICOCHIM MOLEC LAB,CNRS,UA 474,F-64000 PAU,FRANCE
来源：
JOURNAL OF PHYSICAL CHEMISTRY | 1992年 / 96卷 / 12期
关键词：
D O I：
10.1021/j100191a015
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The photoelectron spectrum of iminoacetonitrile (HN=CHCN), obtained by gentle pyrolysis of the sodium salt of 1-cyanoformamide tosylhydrazone at 200-degrees-C, is reported. The first (vertical) ionization potentials are 11.60, 12.34, 13.09, 13.84, and 14.51 eV. These are compared with those of N-cyanomethanimine (CH2=N-CN).
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页码：4801 / 4804
页数：4
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