FORMATION OF COMPLEXES OF COBALT (II) IONS WITH MALEIC ACID ANION IN AQUEOUS - ETHANOL SOLUTIONS

被引：0
|
作者：
Tukumova, N. V. [1 ]
Usacheva, T. R. [1 ]
Thuan, Chan [1 ]
Sharnin, V. A. [1 ]
机构：
[1] Ivanovo State Univ Chem Technol, Ivanovo, Russia
来源：
IZVESTIYA VYSSHIKH UCHEBNYKH ZAVEDENII KHIMIYA I KHIMICHESKAYA TEKHNOLOGIYA | 2012年 / 55卷 / 09期
关键词：
maleic acid; stability constant; coordination compounds; solvation contribution;
D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The composition and stability of complex compounds of cobalt (II) ions with maleic acid anion in aqueous-ethanol solutions was determined by means of potentiometric titration at 298.15 K and ion force of I=0.1 (NaClO4). The increase in the stability for mono complex of Co2+ with maleic acid anion occurs under the increase in ethanol content in solution. The results obtained were compared with the literature data on related compounds. The ions of Co2+ were found to form with the anion of maleic acid less stable complexes than Ni2+ at studied compositions of solvent that corresponds to the conventional Irving-Williams series.
引用
收藏
页码：16 / +
页数：5
相关论文
共 50 条
  • [21] FORMATION OF ACETALDEHYDE IN PHOTOCATALYTIC LIBERATION OF HYDROGEN FROM AQUEOUS ETHANOL SOLUTIONS OF CYANIDE-CONTAINING COBALT COMPLEXES
    MYAKONKII, AG
    MAKHONINA, EV
    ROZENKEVICH, MB
    FALKENGOF, AT
    PERVOV, VS
    HIGH ENERGY CHEMISTRY, 1989, 23 (03) : 206 - 210
  • [22] Complexation of cobalt(II) with thiocyanate ions in aqueous solutions of nonionogenic surfactants
    Amirov, RR
    Skvortsova, EA
    Saprykova, ZA
    RUSSIAN JOURNAL OF COORDINATION CHEMISTRY, 2003, 29 (08) : 554 - 558
  • [23] FORMATION OF SCANDIUM COMPLEXES WITH THIOCYANATE-IONS IN AQUEOUS SOLUTIONS
    SAS, TM
    GAGARINA, VA
    KOMISSAR.LN
    GULIA, VG
    ZHURNAL NEORGANICHESKOI KHIMII, 1970, 15 (05): : 1255 - &
  • [24] Complexation of Cobalt(II) with Thiocyanate Ions in Aqueous Solutions of Nonionogenic Surfactants
    R. R. Amirov
    E. A. Skvortsova
    Z. A. Saprykova
    Russian Journal of Coordination Chemistry, 2003, 29 : 554 - 558
  • [25] COMPLEX-FORMATION OF LANTHANIDE IONS WITH ANTIPYRINE IN AQUEOUS AND ETHANOL SOLUTIONS
    TISHCHENKO, MA
    GERASIMENKO, GI
    POLUEKTOV, NS
    ZHURNAL FIZICHESKOI KHIMII, 1977, 51 (03): : 633 - 636
  • [26] COPPER(II), NICKEL(II) AND COBALT(II) COMPLEXES WITH POLYACRYLAMIDOXIME IN AQUEOUS-SOLUTIONS
    KHOLIN, YV
    BUGAEVSKII, AA
    MIROSHNIK, LV
    KRASOVITSKII, AV
    KOORDINATSIONNAYA KHIMIYA, 1989, 15 (01): : 39 - 43
  • [27] ON THE REACTION BETWEEN COBALT(II) AND AZIDE IONS IN AQUEOUS AND AQUEOUS-ORGANIC SOLUTIONS
    SENISE, P
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1959, 81 (16) : 4196 - 4199
  • [28] Composition, stability, and structure of Cu(II)), Ni(II), and Co(II) complexes with adipic acid dihydrazide in aqueous and aqueous-ethanol solutions
    Afanas'eva, G. V.
    Bychkova, T. I.
    Shtyrlin, V. G.
    Shakirova, A. R.
    Zakharov, A. V.
    RUSSIAN JOURNAL OF GENERAL CHEMISTRY, 2006, 76 (05) : 757 - 765
  • [29] Composition, stability, and structure of Cu(II), Ni(II), and Co(II) complexes with adipic acid dihydrazide in aqueous and aqueous-ethanol solutions
    G. V. Afanas’eva
    T. I. Bychkova
    V. G. Shtyrlin
    A. R. Shakirova
    A. V. Zakharov
    Russian Journal of General Chemistry, 2006, 76 : 757 - 765
  • [30] Interaction of Polyacrylic Acid with Copper, Cobalt, and Nickel Ions in Aqueous Solutions
    Chevtaev, A. S.
    Tabunshchikov, A. I.
    Ozerin, A. S.
    Radchenko, F. S.
    Novakov, I. A.
    RUSSIAN JOURNAL OF GENERAL CHEMISTRY, 2020, 90 (05) : 870 - 873
12345