Stanley Wawzonek and the Introduction of Polar Aprotic Solvents into Organic Electrochemistry

被引：1

作者：

Fry, Albert J. ^{[1
]}

机构：

[1] Univ Wisconsin, Organ Chem, Madison, WI 53706 USA

来源：

ELECTROCHEMICAL SOCIETY INTERFACE | 2010年 / 19卷 / 01期

关键词：

D O I：

10.1149/2.F09101if

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

Stilbene, anthracene, and 9-anisylidenefluorene are reduced stepwise polarographically in anhydrous acetonitrile and in dimethylformamide. Triphenylethylene, tetraphenylethylene, styrene, and 1,1-diphenylethylene give only one reduction wave. Large-scale electrolytic reductions in these solvents indicate that carbanion intermediates exist for a short period of time. 1,2,3,4-Tetraphenylbutane and meso-diphenyl succinic acid have been prepared electrolytically from stilbene in dimethylformamide.

引用

页码：55 / 58

页数：4

共 24 条

[1] THE POLAROGRAPHY OF POLYCYCLIC AROMATIC HYDROCARBONS AND THE RELATIONSHIP BETWEEN THEIR HALF-WAVE POTENTIALS AND ABSORPTION SPECTRA [J].