COORDINATION CHEMISTRY OF PHOSPHORUS(III) AND PHOSPHORUS(V) HYDRAZIDES

被引：33

作者：

KATTI, KV ^{[1
]}

REDDY, VS ^{[1
]}

SINGH, PR ^{[1
]}

机构：

[1] UNIV MISSOURI,CTR RADIOL RES,COLUMBIA,MO 65203

来源：

CHEMICAL SOCIETY REVIEWS | 1995年 / 24卷 / 02期

关键词：

D O I：

10.1039/cs9952400097

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The main group chemistry of phosphorus(III) and phosphorus(V) hydrazides is described. Specifically, the synthesis and characterization of several phosphorus(III) hydrazides of the general formula: R(2)P-N(R')-N(R')-PR(2) and phosphorus(V) hydrazides of the type: R(2)P(E)(NMeNH(2)), RP(E)(NMeNH(2))(2), and P(E)(NMeNH(2))(3)(E=S, O) and their Schiff base adducts are summarized. The transition metal chemistry of phosphorus(III) hydrazides with the early and late transition metals (e.g. Mo-0, W-0, Rh-I, Pd-II, and Pt-II) reveal mononuclear coordination interaction of the two phosphine centres with the metal centres. The coordination chemistry of phosphorus(V) hydrazides demonstrates the versatility of their banding with the transition metals.

引用

页码：97 / 107

页数：11

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