EPITAXIAL-GROWTH AND PHOTOPOLYMERIZATION OF DIACETYLENE FILMS ON ORIENTED LAYERS OF POLY(TETRAFLUOROETHYLENE)

被引：15
作者：
MEYER, S
SMITH, P
WITTMANN, JC
机构：
[1] Institut Charles Sadron, 67083 Strasbourg
来源：
JOURNAL OF APPLIED PHYSICS | 1995年 / 77卷 / 11期
关键词：
D O I：
10.1063/1.359208
中图分类号：
O59 [应用物理学];
学科分类号：
摘要：
Highly oriented polydiacetylene thin films were prepared by epitaxial polymerization of vacuum deposited monomer 5,7-dodecadiyne 1,12 diol bis{[(4-butoxy carbonyl) methyl] urethane} (4-BCMU) on friction-transferred poly(tetrafluoroethylene) (PTFE) substrates. Detailed structural and morphological studies were performed using UV-dichroism measurements, optical and transmission electron microscopy, and suggest that 4-BCMU grows epitaxially on PTFE as a result of a near perfect lattice matching. The oriented monomer layer is converted by photopolymerization into a highly oriented polymer layer with a unique poly(4-BCMU)/PTFE chain to chain orientation and a well defined ac contact plane. Annealing of the monomer layer, prior to photopolymerization, is shown to strongly enhance the final degree of ordering of the polydiacetylene thin films. © 1995 American Institute of Physics.
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页码：5655 / 5660
页数：6
相关论文
共 13 条
[1]  
Bloor D., 1985, NATO ASI SERIES E, V102
[2]   QUASI-EPITAXIAL GROWTH OF DIACETYLENE FILMS BY VACUUM DEPOSITION [J].
KANETAKE, T ;
TOMIOKA, Y ;
IMAZEKI, S ;
TANIGUCHI, Y .
JOURNAL OF APPLIED PHYSICS, 1992, 72 (03) :938-947
[3]   HIGHLY ORIENTED POLYDIACETYLENE FILMS BY VACUUM DEPOSITION [J].
KANETAKE, T ;
ISHIKAWA, K ;
KODA, T ;
TOKURA, Y ;
TAKEDA, K .
APPLIED PHYSICS LETTERS, 1987, 51 (23) :1957-1959
[4]   SINGLE ORIENTATION IN POLY(DIACETYLENE) FILMS FOR NONLINEAR OPTICS - MOLECULAR EPITAXY OF 1,6-BIS(9-CARBAZOLYL)-2,4-HEXADIYNE ON ORGANIC-CRYSTALS [J].
LEMOIGNE, J ;
KAJZAR, F ;
THIERRY, A .
MACROMOLECULES, 1991, 24 (09) :2622-2628
[5]   MORPHOLOGY, LINEAR AND NONLINEAR OPTICAL STUDIES OF POLY[1,6-DI(N-CARBAZOLYL)-2,4 HEXADIYNE] THIN-FILMS (PDCH) [J].
LEMOIGNE, J ;
THIERRY, A ;
CHOLLET, PA ;
KAJZAR, F ;
MESSIER, J .
JOURNAL OF CHEMICAL PHYSICS, 1988, 88 (10) :6647-6654
[6]   EPITAXIAL-GROWTH OF ALIGNED POLYDIACETYLENE FILMS ON ANISOTROPIC ORIENTING POLYMERS [J].
PATEL, JS ;
LEE, SD ;
BAKER, GL ;
SHELBURNE, JA .
APPLIED PHYSICS LETTERS, 1990, 56 (02) :131-133
[7]  
Peterson I. R., 1987, Journal of Molecular Electronics, V3, P103
[8]   THE FORMATION OF SINGLE-CRYSTAL FILMS OF POLYDIACETYLENES [J].
RICKERT, SE ;
LANDO, JB ;
CHING, S .
MOLECULAR CRYSTALS AND LIQUID CRYSTALS, 1983, 93 (1-4) :307-314
[9]   THIN SINGLE-CRYSTAL FILMS OF ORGANICS - WAVEGUIDING IN PTS FILMS [J].
THAKUR, M ;
SHANI, Y ;
CHI, GC ;
OBRIEN, K .
SYNTHETIC METALS, 1989, 28 (03) :D595-D604
[10]  
THIERRY A, 1992, PROG COLLOID POLYM S, V87, P107
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