VERY-LOW-PRESSURE PYROLYSIS (VLPP) OF GROUP IV(A) TETRAMETHYLS - NEOPLENTANE AND TETRAMETHYLTIN

被引：36
作者：
BALDWIN, AC
LEWIS, KE
GOLDEN, DM
机构：
[1] Thermochemistry and Chemical Kinetics Group, Sri International, Menlo Park, California
来源：
INTERNATIONAL JOURNAL OF CHEMICAL KINETICS | 1979年 / 11卷 / 05期
关键词：
D O I：
10.1002/kin.550110506
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The decomposition of neopentane was studied using the very‐low‐pressure pyrolysis (VLPP) technique at temperatures from 1000 to 1260 K. The derived Arrhenius parameters (Formula Presented.) are consistent with δHf0(t‐butyl) = 8.4 kcal/mol. Using the above A factor, data on the decomposition of tetramethyltin yield DH0(Sn(CH3)3 ‐ CH3) = 69 ± 2 kcal/mol. Copyright © 1979 John Wiley & Sons, Inc.
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页码：529 / 542
页数：14
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