ATTACK OF TRIMETHYLPHOSPHITE UPON AETA-6-BENZENE LIGAND TO GIVE 2-6ETA-1-EXO-DIMETHOXYPHOSPHORYLCYCLO-HEXADIENYL(ETA5-ETHYLTETRAMETHYLCYCLOPENTADIENYL)-RHODIUM(III) HEXAFLUOROPHOSPHATE

被引：6

作者：

FAIRHURST, G

WHITE, C

机构：

[1] Department of Chemistry, The University, Sheffield

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1979年 / 166卷 / 01期

关键词：

D O I：

10.1016/S0022-328X(00)91432-3

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The title compound has been prepared by reaction of trimethylphosphite with η6 -benzene(σ5 -ethyltetramethylcyclopentadienyl)rhodium(III) hexafluorophosphate. IR and 1H, 13C and 31P NMR spectra of the product are reported. © 1979.

引用

页码：C23 / C25

页数：3

共 11 条

[1] (ETA-6-BENZENE)(ETA-5-ETHYLTETRAMETHYLCYCLOPENTADIENYL)RHODIUM (III) HEXAFLUOROPHOSPHATE - A REAGENT FOR CATALYTIC PHENOL OXIDATIVE COUPLING
BARRETT, AGM
ITOH, T
WALLACE, EM
TETRAHEDRON LETTERS, 1993, 34 (14) : 2233 - 2234
[2] REACTIONS OF THE ETA6-BENZENE(ETA5-ETHYLTETRAMETHYLCYCLOPENTADIENYL)-RHODIUM(III) CATION AND RELATED SPECIES WITH NUCLEOPHILES - THE CRYSTAL-STRUCTURE OF [RH(ETA5-C5ME4ET)(ETA5-C6H6P(O)(OME)2)][PF6]
BAILEY, NA
BLUNT, EH
FAIRHURST, G
WHITE, C
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1980, (05): : 829 - 836
[3] ORGANOMETALLIC RHODIUM(III) AND RHODIUM(I) COMPLEXES WITH 1,3-DIMETHYLLUMAZINE(DML) - THE CRYSTAL-STRUCTURE OF [(ETA(2)-(O-4,N-5)DML)(ETA(5)-C(5)ME(5))CLRH](PF6)
HEILMANN, O
HAUSEN, HD
KAIM, W
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 1994, 49 (11): : 1554 - 1560
[4] PREPARATION AND STUDY OF FUNCTIONALIZED 1,2,4-TRIAZINE DERIVATIVES OF THE (ETA(6)-ARENE)RU-II (ARENE=BENZENE OR P-CYMENE) AND (ETA(5)-C(5)ME(5))RH-III MOIETIES
GARCIA, G
SOLANO, I
SANCHEZ, G
LOPEZ, G
CASABO, J
MOLINS, E
MIRAVITLLES, C
POLYHEDRON, 1995, 14 (13-14) : 1855 - 1863
[5] FURTHER-STUDIES ON METAL-PROMOTED VINYLCYCLOPROPANE TO CYCLOPENTENE REARRANGEMENTS - STRUCTURE AND THERMOLYSIS OF RHODIUM COMPLEXES OF EXO-6-VINYLBICYCLO[3.1.0]HEX-2-ENE AND THE CRYSTAL-STRUCTURE OF THE 1,6-8-ETA-4-5-ALLYLCYCLOPENT-2-ENYL(HEXAFLUOROACETYLACETONATO)RHODIUM(III) TETRAMER
ALCOCK, NW
BROWN, JM
CONNEELY, JA
WILLIAMSON, DH
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1979, (07): : 962 - 971
[6] FORMATION OF ETA-1-IMINOACYL COMPOUNDS BY INSERTION OF ISONITRILES IN PENTAMETHYLCYCLOPENTADIENYL TETRAMETHYLFULVENE COMPOUNDS OF TITANIUM AND ZIRCONIUM - INTRAMOLECULAR C-H ACTIVATION OF A PENTAMETHYLCYCLOPENTADIENYL GROUP TO GIVE A TRIDENTATE LIGAND WITH 2 BRIDGED CYCLOPENTADIENYL RINGS AND A TITANIUM VINYL BOND IN THE BRIDGE - MOLECULAR-STRUCTURE OF [ETA-5-ETA-1-ETA-5-C5ME4CH2C(NHXYL)=CN(XYL)CH2C5ME4]TICL AND CP-STAR-[ETA-5-ETA-1-C5ME4CH2C(=NXYL)C(=NXYL)]ZRCL (XYL = 2,6-ME2C6H3)
FANDOS, R
MEETSMA, A
TEUBEN, JH
ORGANOMETALLICS, 1991, 10 (08) : 2665 - 2671
[7] The first metal complexes containing the 1,4-cyclohexa-2,5-dienyl ligand (benzene 1,4-dianion); Synthesis and structures of [K(18-crown-6)][Ln{eta(5)-C5H3(SiMe(3))(2)(C6H6)] (Ln=La, Ce)
Cassani, MC
Gunko, YK
Hitchcock, PB
Lappert, MF
CHEMICAL COMMUNICATIONS, 1996, (16) : 1987 - 1988
[8] STRUCTURAL CHARACTERIZATION OF POLY(1-PYRAZOLYL)BORATE-METAL AND POLY(1-PYRAZOLYL)METHANE-METAL COMPLEXES CONTAINING CARBOCYCLIC PI-ACCEPTOR LIGANDS - SYNTHESIS AND CRYSTAL AND MOLECULAR-STRUCTURES OF [TETRAKIS(1-PYRAZOLYL)BORATO](ETA6-BENZENE)RUTHENIUM(II) HEXAFLUOROPHOSPHATE AND [HYDROTRIS(1-PYRAZOLYL)BORATO](ETA5-PENTAMETHYLCYCLOPENTADIENYL)RHODIUM(II) HEXAFLUOROPHOSPHATEA
RESTIVO, RJ
FERGUSON, G
OSULLIVAN, DJ
LALOR, F
INORGANIC CHEMISTRY, 1975, 14 (12) : 3046 - 3052
[9] MECHANISMS OF NUCLEOPHILIC-ATTACK AT COORDINATED CARBON-MONOXIDE .2. IODIDE ADDITION TO A CARBON-MONOXIDE LIGAND IN [FE(CO3(1-5-ETA-DIENYL)]+ CATIONS (DIENYL = C6H7,C7H9,2-MEOC6H6)
JOHN, GR
KANEMAGUIRE, LAP
KANITZ, R
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1986, 312 (02) : C21 - C23
[10] METAL VS LIGAND-EXCHANGE UPON REACTION OF [(ETA-5-C5H5)MO(CO)3]- WITH (MU-3-S)CO3(CO)7LX CLUSTERS - A 2-STEP SYNTHESIS OF THE OPTICALLY-ACTIVE CLUSTER (MU-3-S)MO(ETA-5-C5H5)CO2(CO)6[MU-1,2-ETA-2-C(R1)N(R2)]
MAHE, C
PATIN, H
LEMAROUILLE, JY
BENOIT, A
ORGANOMETALLICS, 1983, 2 (08) : 1051 - 1053

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