EXTREME SYMBIOSIS - THE FACILE ONE-STEP SYNTHESIS OF THE PARAMAGNETIC COBALT(III) COMPLEX OF TRIPHENYLANTIMONY, COI(3)(SBPH(3))(2), FROM THE REACTION OF TRIPHENYLANTIMONYDIIODINE WITH UNACTIVATED COARSE-GRAIN COBALT METAL-POWDER

被引：27

作者：

GODFREY, SM

MCAULIFFE, CA

PRITCHARD, RG

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1994年 / 01期

关键词：

D O I：

10.1039/c39940000045

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Triphenylantimony diiodine (2 equiv.) reacts with unactivated cobalt powder to yield the unexpected cobalt(III) complex Col(3)(SbPh(3))(2); this five coordinate species represents a rare example of a paramagnetic cobalt(III) complex.

引用

页码：45 / 46

页数：2

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