SYNTHESIS OF ISOMERICALLY PURE ORGANODIHYDROFULLERENES

被引：233
作者：
HIRSCH, A
GROSSER, T
SKIEBE, A
SOI, A
机构：
[1] Institut Für Organische Chemie, Universität Tübingen, Tübigen, W-7400
来源：
CHEMISCHE BERICHTE-RECUEIL | 1993年 / 126卷 / 04期
关键词：
BUCKMINSTERFULLERENES; ORGANODIHYDROFULLERENES; FULLERENE DERIVATIVES;
D O I：
10.1002/cber.19931260428
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Controlled two-step nucleophilic hydroalkylations, hydroarylations as well as hydrostannylations of fullerene-60 (1) and fullerene-70 (2) lead to defined organodihydrofullerenes Cr60HR and C70HR. NMR investigations show that only one isomer of each organodihydrofullerene with C(s) symmetry is formed. In all cases the addition takes place at a double bond separating two six-membered rings of the fullerene core. In this way a variety of organodihydrofullerenes also carrying functional groups have been synthesized.
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页码：1061 / 1067
页数：7
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