THE FIRST SYNTHESIS OF BISGERMYLENE AND BISSTANNYLENE WITH ACYCLIC STRUCTURE

被引：15

作者：

KOBAYASHI, S

CAO, S

机构：

来源：

CHEMISTRY LETTERS | 1994年 / 05期

关键词：

D O I：

10.1246/cl.1994.941

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A bisgermylene and a bisstannylene with acyclic structure were synthesized for the first time by one-pot, two-step ligand substitution reactions from the corresponding germanium and tin dichlorides. The products were easily isolated by crystallization from diethyl ether and are stable at ambient temperatures under argon. Oxidative addition of the bisgermylene or bisstannylene to organic halides was examined.

引用

收藏

页码：941 / 944

页数：4

相关论文

共 15 条

[1] SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF THE CYCLIC SPECIES [GEN(2,6-ISO-PR2C6H3)]3 - THE 1ST GERMANAZENE [J].

BARTLETT, RA ;

POWER, PP .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1990, 112 (09) :3660-3662

[2] DIBUTYLMAGNESIUM, A CONVENIENT REAGENT FOR THE SYNTHESIS OF USEFUL ORGANIC MAGNESIUM REAGENTS MGA2 INCLUDING CYCLOPENTADIENYLS, ARYLOXIDES, AND AMIDES - PREPARATION OF ZR(C5H5)CL3. X-RAY STRUCTURE OF [MG(MU-N(SIME)3)C6H4N(SIME3)-0)(OET2)]2 [J].

DUFF, AW ;

HITCHCOCK, PB ;

LAPPERT, MF ;

TAYLOR, RG ;

SEGAL, JA .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1985, 293 (03) :271-283

[3] SUBVALENT GROUP 4B METAL ALKYLS AND AMIDES .8. GERMANIUM AND TIN CARBENE ANALOGS MR2[M = GE OR SN, R = CH(SIME3)2] - SYNTHESES AND STRUCTURES IN THE GAS-PHASE (ELECTRON-DIFFRACTION) - MOLECULAR-ORBITAL CALCULATIONS FOR MH2 AND GEME2 [J].

FJELDBERG, T ;

HAALAND, A ;

SCHILLING, BER ;

LAPPERT, MF ;

THORNE, AJ .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1986, (08) :1551-1556

[4] SUBVALENT GROUP-4B METAL ALKYLS AND AMIDES .6. OXIDATIVE ADDITION OF AN ALKYL OR ARYL HALIDE TO BIS[BIS(TRIMETHYLSILYL)METHYL]TIN(II( - H-1 NUCLEAR MAGNETIC-RESONANCE DATA ON TIN(IV) ADDUCTS AND A SINGLE-CRYSTAL X-RAY STUDY OF TRIS[BIS(TRIMETHYLSILYL)METHYL]CHLOROTIN(IV) [J].

GYNANE, MJS ;

LAPPERT, MF ;

MILES, SJ ;

CARTY, AJ ;

TAYLOR, NJ .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1977, (20) :2009-2015

[5] MONOMERIC, VOLATILE BIVALENT AMIDES OF GROUP-IVB ELEMENTS, M(NR12)2 AND M(NR1R2)2 (MDOUBLE-BONDGE, SN, OR PB - R1DOUBLE-BONDME3SI, R2DOUBLE-BONDME3C) [J].

HARRIS, DH ;

LAPPERT, MF .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1974, (21) :895-896

[6] NOVEL 2-COORDINATE GERMANIUM(II) ARYLAMIDES - GE(NHC6H2BU-TERT-3-2,4,6)2, ARN[GE(NHC6H2BU-TERT-3-2,4,6)]2(MU-NC6H2BU-TERT-3-2,4,6) AND [GE(MU-NC6H2BU-TERT-3-2,4,6)]2 2, AND THE X-RAY STRUCTURES OF 2 AND SN(NHC6H2BU-TERT-3-2,4,6)2 [J].

HITCHCOCK, PB ;

LAPPERT, MF ;

THORNE, AJ .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1990, (22) :1587-1589

[7] NEW GERMANIUM-CONTAINING POLYMERS VIA ALTERNATING COPOLYMERIZATION OF A GERMYLENE WITH PARA-BENZOQUINONE DERIVATIVES [J].

KOBAYASHI, S ;

IWATA, S ;

ABE, M ;

SHODA, S .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1990, 112 (04) :1625-1626

[8] COPOLYMERIZATION OF A GERMYLENE WITH ACETYLENE MONOMERS BY RHODIUM CATALYSIS [J].

KOBAYASHI, S ;

CAO, S .

CHEMISTRY LETTERS, 1993, (01) :25-28

[9] SYNTHESIS OF POLYGERMANES BY LIGAND SUBSTITUTION POLYMERIZATION OF THE 1,4-DIOXANE COMPLEX OF GERMANIUM DICHLORIDE WITH ORGANOLITHIUM COMPOUNDS [J].

KOBAYASHI, S ;

CAO, S .

CHEMISTRY LETTERS, 1993, (08) :1385-1388

[10] POLY(GERMANIUM ENOLATE) - A NEW CLASS OF POLYMER HAVING A GERMANIUM ENOLATE STRUCTURE IN THE MAIN CHAIN [J].

KOBAYASHI, S ;

IWATA, S ;

YAJIMA, K ;

YAGI, K ;

SHODA, S .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (12) :4929-4931