Bis(mu-4-methylbenzoato)-kappa O-3,O':O;kappa O-3:O,O'-bis[aqua(4-methylbenzoato-kappa O-2,O') (nicotinamide-kappa N-1)cadmium]

被引：1
作者：
Dincel, Oznur [1 ]
Tercan, Baris [1 ]
Cimen, Efdal [2 ]
Necefoglu, Hacali [2 ]
Hokelek, Tuncer [3 ]
机构：
[1] Karabuk Univ, Dept Phys, TR-78050 Karabuk, Turkey
[2] Kafkas Univ, Dept Chem, TR-36100 Kars, Turkey
[3] Hacettepe Univ, Dept Phys, TR-06800 Ankara, Turkey
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2012年 / 68卷
关键词：
data-to-parameter ratio = 16.3; disorder in main residue; mean ω(C-C) = 0.003 Å; R factor = 0.019; single-crystal X-ray study; T = 100 K; wR factor = 0.048;
D O I：
10.1107/S1600536812047046
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
In the dinuclear centrosymmetric title compound, [Cd-2(C8H7O2)(4)(C6H6N2O)(2)(H2O)(2)], the Cd-II ion is chelated by two carboxylate groups from 4-methylbenzoate anions, and is further coordinated by one nicotinamide and one water molecule; a carboxylate O atom from an adjacent 4-methylbenzoate anion bridges to the Cd-II ion, completing the irregular coordination sphere of the seven ligand atoms. In the crystal, intermolecular O-H center dot center dot center dot O, N-H center dot center dot center dot O and weak C-H center dot center dot center dot O hydrogen bonds link the molecules into a three-dimensional network. The methylbenzene moiety of one bridging 4-methylbenzoate anion is disordered over two orientations of equal occupancy.
引用
收藏
页码：M1510 / +
页数：11
相关论文
共 16 条
[1]  
[Anonymous], 2005, SADABS
[2]   CRYSTAL AND MOLECULAR STRUCTURE OF MONO-(N,N-DIETHYLNICOTINAMIDE)CADMIUM DITHIOCIOCYANATE [J].
BIGOLI, F ;
BRAIBANTI, A ;
TIRIPICCHIO, A ;
PELLINGHELLI, MA .
ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL CRYSTALLOGRAPHY AND CRYSTAL CHEMISTRY, 1972, B 28 (MAR15) :962-+
[3]  
Bruker, 2007, APEX2 SAINT
[4]   WinGX and ORTEP for Windows: an update [J].
Farrugia, Louis J. .
JOURNAL OF APPLIED CRYSTALLOGRAPHY, 2012, 45 :849-854
[5]   CHARACTERIZATION OF A MONONUCLEAR COPPER CARBOXYLATE COMPLEX - BIS(ACETYLSALICYLATO)BIS(PYRIDINE)COPPER(II) [J].
GREENAWAY, FT ;
PEZESHK, A ;
CORDES, AW ;
NOBLE, MC ;
SORENSON, JRJ .
INORGANICA CHIMICA ACTA-BIOINORGANIC CHEMISTRY, 1984, 93 (02) :67-71
[6]   Bis(mu-4-hydroxybenzoato-O:O')-bis[(N,N-diethylnicotinamide-N-1)-(4-hydroxybenzoato-O)zinc(II)] dihydrate [J].
Hokelek, T ;
Necefoglu, H .
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1996, 52 :1128-1131
[7]   Bis[μ-4-(methylamino)benzoato]-κ3O,O′:O;κ3O:O,O′-bis{aqua[4-(methylamino)benzoato-κ2O,O′](nicotinamide-κN)cadmium(II)} [J].
Hokelek, Tuncer ;
Saglam, Ertugrul Gazi ;
Tercan, Baris ;
Aybirdi, Ozgur ;
Necefoglu, Hacali .
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2010, 66 :M1559-U739
[8]   Bis[μ-4-(dimethylamino)benzoato]-κ3O,O′:O;κ3O:O,O′-bis{aqua[4-(dimethylamino)benzoato-κ2O,O′](nicotinamide-κN1)cadmium(II)} [J].
Hokelek, Tuncer ;
Suzen, Yasemin ;
Tercan, Baris ;
Aybirdi, Oezguer ;
Necefoglu, Hacali .
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2010, 66 :M782-U623
[9]   Aquabis(4-formylbenzoato-κ2O1,O1′)bis(isonicotinamide-κN1)cadmium(II) monohydrate [J].
Hokelek, Tuncer ;
Yilmaz, Filiz ;
Tercan, Baris ;
Gurgen, Ferdi ;
Necefoglu, Hacali .
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2009, 65 :M1416-U1594
[10]   Bis(isonicotinamide-κN1)bis[4-(methylamino)benzoato]zinc(II) monohydrate [J].
Hokelek, Tuncer ;
Dal, Hakan ;
Tercan, Baris ;
Aybirdi, Ozgur ;
Necefoglu, Hacali .
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2009, 65 :M1365-U1159
12