A GERMANIUM SESQUISULFIDE, (TERT-BUGE)4S6, WITHOUT ADAMANTANE STRUCTURE

被引：39

作者：

ANDO, W ^{[1
]}

KADOWAKI, T ^{[1
]}

KABE, Y ^{[1
]}

ISHII, M ^{[1
]}

机构：

[1] NATL INST RES INORGAN MAT,TSUKUBA,IBARAKI 305,JAPAN

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1992年 / 31卷 / 01期

关键词：

D O I：

10.1002/anie.199200591

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Two sulfur-bridged, almost planar Ge2S2, four-membered rings are found in the novel sesquichalcogenide 1, which is formed from the reaction of tBuGeCl3 with (NH4)2S5. Due to thermal strain, 1, rearranges to the known (tBuGe)4S6 isomer with an adamantane framework. If this second compound is prepared directly from tBuGeCl3 and H2S/pyridine, bisgermanium thiolates are detected as intermediates.

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页码：59 / 61

页数：3

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