CATION EFFECTS IN NUCLEAR QUADRUPOLE RESONANCE SPECTROSCOPY

被引：10

作者：

SMITH, PW

STOESSIGER, R

机构：

[1] Chemistry Department, University of Tasmania, Hobart, TAS

来源：

MOLECULAR PHYSICS | 1969年 / 17卷 / 05期

关键词：

D O I：

10.1080/00268976900101341

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A method for calculating the lattice contribution to the field gradient at a point in a crystal is outlined and is applied to the calculation of the chlorine N.Q.R. frequency difference between K2PtCl6 and Cs2PtCl6. Closer agreement with the experimental value is obtained as compared with a previous calculation but complete agreement is not obtained using any reasonable value for the quadrupole antishielding factor. The importance of the lattice contribution to the individual N.Q.R. frequencies is also discussed. © 1969 Taylor and Francis Group, LLC.

引用

页码：503 / +

页数：1

共 14 条

[1] ANTISHIELDING AND CONTRACTED WAVE FUNCTIONS [J].