EFFICIENT ELECTROPHILIC FLUORINATION OF BETA-DICARBONYL COMPOUNDS WITH THE SELECTFLUOR REAGENT F-TEDA-BF4 (1-CHLOROMETHYL-4-FLUORO-1,4-DIAZONIABICYCLO[2.2.2]OCTANE BIS(TETRAFLUOROBORATE))

被引：91
作者：
BANKS, RE
LAWRENCE, NJ
POPPLEWELL, AL
机构：
来源：
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1994年 / 03期
关键词：
D O I：
10.1039/c39940000343
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
1,3-Dicarbonyl compounds (acyclic and cyclic 1,3-diketones, beta-ketoesters, beta-ketoamides) are converted efficiently to 2-monofluoro derivatives, and thence to 2,2-difluoro derivatives, with 1-chloromethyl-4-fluoro-1,4-diazoniabicyclo[2.2.2]octane bis(tetrafluoroborate).
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页码：343 / 344
页数：2
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