EFFICIENT ELECTROPHILIC FLUORINATION OF BETA-DICARBONYL COMPOUNDS WITH THE SELECTFLUOR REAGENT F-TEDA-BF4 (1-CHLOROMETHYL-4-FLUORO-1,4-DIAZONIABICYCLO[2.2.2]OCTANE BIS(TETRAFLUOROBORATE))

被引：91

作者：

BANKS, RE

LAWRENCE, NJ

POPPLEWELL, AL

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1994年 / 03期

关键词：

D O I：

10.1039/c39940000343

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

1,3-Dicarbonyl compounds (acyclic and cyclic 1,3-diketones, beta-ketoesters, beta-ketoamides) are converted efficiently to 2-monofluoro derivatives, and thence to 2,2-difluoro derivatives, with 1-chloromethyl-4-fluoro-1,4-diazoniabicyclo[2.2.2]octane bis(tetrafluoroborate).

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页码：343 / 344

页数：2

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