THE CONFIRMATION OF THE FORMATION OF CLATHRATE-LIKE HYDRATES OF POLY(TETRABUTYLAMMONIUM ETHENESULFONATE) AND OF POLY(TETRAISOPENTYLAMMONIUM ETHENESULFONATE)

被引：1

作者：

NAKAYAMA, H

YAMANOBE, M

BABA, K

机构：

[1] Division of Materials Science and Chemical Engineering, Faculty of Engineering, Yokohama National University, Yokohama, 240, Tokiwadai, Hodogaya-ku

来源：

JOURNAL OF THERMAL ANALYSIS | 1993年 / 40卷 / 02期

关键词：

CLATHRATE-LIKE HYDRATES; DSC;

D O I：

10.1007/BF02546613

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

A thermal method using differential scanning calorimeter has been applied to aqueous solutions of a series of poly(tetraalkylammonium ethenesulfonates) (R4NPES). It was found that only the salts with R =n-C4H9 and R =i-C5H11 could form stable hydrates having large hydration numbers. The melting point and hydration numbers of these two hydrates were 12.0-degrees-C and 30+/-1 for the (n-C4H9)4NPES hydrate and 16.0-degrees-C and 53+/-2 for the (i-C5H11)4NPES hydrate, respectively. It was concluded that these hydrates were clathrate-like essentially similar to such hydrates as (n-C4H9)4NF.30H2O and (i-C5H11)4NF.40H2O.

引用

页码：445 / 451

页数：7

共 12 条

[1]

BONAMICO M, 1962, J CHEM PHYS, V37, P219

[2] POLYMERS AND COPOLYMERS OF SODIUM ETHYLENESULFONATE [J].

BRESLOW, DS ;

KUTNER, A .

JOURNAL OF POLYMER SCIENCE, 1958, 27 (115) :295-312

[3]

DIALER K, 1956, MAKROMOL CHEM, V17, P56

[4] POLYHEDRAL CLATHRATE HYDRATES .2. STRUCTURE OF HYDRATE OF TETRA ISO-AMYL AMMONIUM FLUORIDE [J].

FEIL, D ;

JEFFREY, GA .

JOURNAL OF CHEMICAL PHYSICS, 1961, 35 (05) :1863-&

[5] Some unusual hydrates of quaternary ammonium salts [J].

Fowler, DL ;

Loebenstein, WV ;

Pall, DB ;

Kraus, CA .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1940, 62 :1140-1142

[6]

KERN W, 1959, MAKROMOLEKUL CHEM, V32, P37

[7] POLYHEDRAL CLATHRATE HYDRATES .5. STRUCTURE OF TETRA-N-BUTYL AMMONIUM FLUORIDE HYDRATE [J].

MCMULLAN, RK ;

JEFFREY, GA ;

BONAMICO, M .

JOURNAL OF CHEMICAL PHYSICS, 1963, 39 (12) :3295-&

[8] HYDRATES OF ORGANIC-COMPOUNDS .7. THE EFFECT OF ANIONS ON THE FORMATION OF CLATHRATE HYDRATES OF TETRABUTYLAMMONIUM SALTS [J].

NAKAYAMA, H .

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1983, 56 (03) :877-880

[9] HYDRATES OF ORGANIC-COMPOUNDS .13. THE CONFIRMATION OF THE FORMATION OF CLATHRATE-LIKE HYDRATES OF TETRABUTYLAMMONIUM AND OF TETRAISOPENTYLAMMONIUM POLYACRYLATES [J].

NAKAYAMA, H .

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1987, 60 (07) :2319-2326

[10] HYDRATES OF ORGANIC-COMPOUNDS .16. DETERMINATION OF THE MELTING-POINTS AND HYDRATION NUMBERS OF THE HYDRATES OF TETRABUTYL(OR TETRAISOPENTYL)AMMONIUM ALKANESULFONATES [J].

NAKAYAMA, H ;

YAMANOBE, M ;

BABA, K .

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1991, 64 (10) :3023-3028

← 1 2 →