COMPARATIVE DEACTIVATION STUDY OF NICKEL AND PALLADIUM CATALYSTS IN LIQUID-PHASE HYDROGENATION

被引：0
|
作者：
ALPHONSE, P
MOYEN, F
GALLETTI, D
MAURET, P
机构：
来源：
JOURNAL DE CHIMIE PHYSIQUE ET DE PHYSICO-CHIMIE BIOLOGIQUE | 1992年 / 89卷 / 10期
关键词：
D O I：
10.1051/jcp/1992892029
中图分类号：
Q5 [生物化学]; Q7 [分子生物学];
学科分类号：
071010 ; 081704 ;
摘要：
In previous work [1] we have pointed out the very high toxicity of mercuric iodide (HgI2) towards unsupported nickel and palladium particles in 1-hexene hydrogenation. Moreover, for both catalysts, we found that poison molecules number required for total deactivation was close to metal particles vertices number. In this paper we compare our previous results with new experimental data obtained with other catalysts, other reactants and another poison.
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页码：2029 / 2044
页数：16
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