4M LITHIUM PERCHLORATE-NITROMETHANE - AN EFFICIENT SOLVENT IN DIELS-ALDER REACTIONS USING NITROALKENES AS DIENOPHILES

被引：41

作者：

AYERBE, M ^{[1
]}

COSSIO, FP ^{[1
]}

机构：

[1] EUSKAL HERRIKO UNIBERTSITATEA,FAK KIM,E-20080 SAN SEBASTIAN DON,SPAIN

来源：

TETRAHEDRON LETTERS | 1995年 / 36卷 / 25期

关键词：

D O I：

10.1016/0040-4039(95)00678-6

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Diels-Alder reactions in which nitroalkenes act as dienophiles are substantially accelerated in 4M lithium perchlorate-nitromethane solutions. This acceleration is higher than that observed when the known 5M lithium perchlorate-diethyl ether system is used.

引用

页码：4447 / 4450

页数：4

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