PYROLYSIS OF HIGH-BOILING PETROLEUM FRACTIONS

被引：8

作者：

SEBOR, G ^{[1
]}

BLAZEK, J ^{[1
]}

LEDERER, J ^{[1
]}

RICANEK, M ^{[1
]}

NOVAK, V ^{[1
]}

机构：

[1] CHEM WORKS, CS-43670 LITVINOV, CZECHOSLOVAKIA

来源：

FUEL | 1992年 / 71卷 / 11期

关键词：

PYROLYSIS; PETROLEUM; FRACTIONS;

D O I：

10.1016/0016-2361(92)90048-S

中图分类号：

TE [石油、天然气工业]; TK [能源与动力工程];

学科分类号：

0807 ; 0820 ;

摘要：

Hydrocracking of a petroleum vacuum distillate was carried out under a pressure of 15 MPa and temperatures of 390, 410, and 420-degrees-C on a Ni-W/aluminosilicate catalyst. Both the vacuum distillate and the high-boiling products of its hydrocracking were subjected to pyrolysis to yield light alkenes. The pyrolysis feedstocks were analysed by a procedure consisting in separation by liquid adsorption chromatography and subsequent characterization by elemental analysis, vapour pressure osmometry, H-1 and C-13 n.m.r. spectrometry, and mass spectrometry. The relation between chemical structure and composition of the materials used for pyrolysis on the one hand and the yield of light alkenes on the other hand is discussed.

引用

页码：1231 / 1237

页数：7

共 17 条

[1]

CHAVEROT P, 1986, REV I FR PETROL, V41, P529

[2]

CHAVEROT P, 1986, REV I FR PETROL, V41, P649

[3] NUCLEAR MAGNETIC-RESONANCE SPECTROMETRY OF PETROLEUM FRACTIONS - C-13 AND PROTON NUCLEAR MAGNETIC-RESONANCE CHARACTERIZATIONS IN TERMS OF ERAGE MOLECULE PARAMETERS [J].

CLUTTER, DR ;

PETRAKIS, L ;

STENGER, RL ;

JENSEN, RK .

ANALYTICAL CHEMISTRY, 1972, 44 (08) :1395-&

[4]

GOETZMANN S, 1979, HYDROCARB PROCESS, V58, P109

[5]

GOOSSENS AG, 1986, HYDROCARB PROCESS, V65, P84

[6]

GREEN EJ, 1975, HYDROCARB PROCESS, V54, P164

[7]

KAISER V, 1984, OIL GAS J, V82, P66

[8]

KHARITONOV BE, 1986, NEFTEKHIMIYA, V26, P522

[9]

NAHAS RS, 1981, CHEM ECON ENG REV, V13, P13

[10]

NOWAK S, 1990, STUD SURF SCI CATAL, V53, P103

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