ISOLATION AND X-RAY STRUCTURE DETERMINATION OF A SULFUR-BRIDGED INCOMPLETE CUBANE-TYPE MOLYBDENUM(IV) AQUA CLUSTER, [MO3S4(H2O)9](CH3.C6H4.SO3)4.9H2O

被引：65

作者：

AKASHI, H ^{[1
]}

SHIBAHARA, T ^{[1
]}

KUROYA, H ^{[1
]}

机构：

[1] OKAYAMA UNIV SCI,DEPT CHEM,1-1 RIDAI CHO,OKAYAMA 700,JAPAN

来源：

POLYHEDRON | 1990年 / 9卷 / 14期

关键词：

D O I：

10.1016/S0277-5387(00)83970-4

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The title compound was isolated in high yield (72%) from 4 M HPTS solution, and the X-ray crystal structure has been determined. The cluster cation has an approximate C3ν, symmetry. The average MoMo distance (2.735[8] Å) in the aqua complex is the shortest reported in complexes with Mo3S4 cores so far. Every SO3- moiety of the pts- anion faces towards the complex cation. © 1990.

引用

页码：1671 / 1676

页数：6

共 36 条

[1] NOVEL CUBANE-TYPE MOLYBDENUM TIN CLUSTER COMPLEXES [(H2O)9MO3S4SNS4MO3(H2O)9]8+ AND MO3SNS4(AQ)6+ [J].

AKASHI, H ;

SHIBAHARA, T .

INORGANIC CHEMISTRY, 1989, 28 (15) :2906-2907

[2] OXALATO COMPLEXES OF THE TRINUCLEAR AQUO ION OF MOLYBDENUM(IV), [MO3O4]4+ [J].

BENORY, E ;

BINO, A ;

GIBSON, D ;

COTTON, FA ;

DORI, Z .

INORGANICA CHIMICA ACTA-ARTICLES AND LETTERS, 1985, 99 (02) :137-142

[3] THE MO3S44+ AQUO ION [J].

COTTON, FA ;

DORI, Z ;

LLUSAR, R ;

SCHWOTZER, W .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1985, 107 (23) :6734-6735

[4] TRIANGULAR TRINUCLEAR CLUSTER COMPOUNDS - MOLYBDENUM AND TUNGSTEN COMPLEXES OF THE TYPE [M3S4(DIPHOS)3CL3]+, [M3S4(DIPHOS)3H3]+ [J].

COTTON, FA ;

LLUSAR, R ;

EAGLE, CT .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (12) :4332-4338

[5] DIRECT SYNTHESIS FROM MOCL3(THF)3 OF A COMPLEX CONTAINING THE [MO3S4]4+ CORE [J].

COTTON, FA ;

LLUSAR, R .

POLYHEDRON, 1987, 6 (09) :1741-1745

[6] A NEW REACTION CONVERTING THE MO3(MU-3-S)(MU-S2)3 CORE TO THE MO3(MU-3-S)(MU-S)3 CORE - STRUCTURE OF THE [MO3(MU-3-S)(MU-S)3[N(CH2CO2)3(H)2]3- ION [J].

COTTON, FA ;

LLUSAR, R ;

MARLER, DO ;

SCHWOTZER, W .

INORGANICA CHIMICA ACTA-ARTICLES AND LETTERS, 1985, 102 (01) :L25-L27

[7] OXIDATIVE FRAGMENTATION OF THE CUBOID MO4S4 CLUSTER CORE - SYNTHESIS AND STRUCTURES OF [MO3(MU-3-S)(MU-S)3([9]ANE3)3]4+ AND [[MOO([9]ANEN3)]2(MU-S)2]2+ [J].

COTTON, FA ;

DORI, Z ;

LLUSAR, R ;

SCHWOTZER, W .

INORGANIC CHEMISTRY, 1986, 25 (20) :3654-3658

[8] A MIXED OXO THIO-BRIDGED TRITUNGSTEN TRIANGULAR CLUSTER COMPLEX [J].

DORI, Z ;

COTTON, FA ;

LLUSAR, R ;

SCHWOTZER, W .

POLYHEDRON, 1986, 5 (03) :907-909

[9] SYNTHESIS, STRUCTURE, AND REACTIVITY OF [(C2H5)4N]2[MO3(MU-3-S)(MU-2-S)3(SCH2CH2S)3] - A CLUSTER WITH SULFUR VACANCIES AND RESONANCE RAMAN SPECTRAL SIMILARITY TO FE3S4 PROTEINS [J].

HALBERT, TR ;

MCGAULEY, K ;

PAN, WH ;

CZERNUSZEWICZ, RS ;

STIEFEL, EI .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1984, 106 (06) :1849-1851

[10] STRUCTURE AND REDOX PROPERTIES OF THE MOLYBDENUM(IV) METAL CLUSTER K5[MO3S4(CN)9].7H2O [J].

HOWLADER, NC ;

HAIGHT, GP ;

HAMBLEY, TW ;

LAWRANCE, GA ;

RAHMOELLER, KM ;

SNOW, MR .

AUSTRALIAN JOURNAL OF CHEMISTRY, 1983, 36 (02) :377-383

← 1 2 3 4 →