BINUCLEAR DIOXOMOLYBDENUM(VI) COMPLEXES CONTAINING BRIDGING DIOXIME SCHIFF-BASE LIGANDS

被引：12

作者：

MOHANTY, RN ^{[1
]}

DASH, KC ^{[1
]}

机构：

[1] UTKAL UNIV,DEPT CHEM,BHUBANESWAR 751004,ORISSA,INDIA

来源：

POLYHEDRON | 1990年 / 9卷 / 08期

关键词：

D O I：

10.1016/S0277-5387(00)81286-3

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

MoO2(acac)2 reacts in EtOH with polydentate dioxime-based Schiff base ligands obtained by the condensation of biacetylmonoxime with ethylenediamine (H2DMED), propylenediamine (H2DMPD), diethylenetriamine (H2DMDT) and triethylenetetramine (H2DMTT) to form binuclear, ligand-bridged, six-coordinated cis-dioxomolybdenum(VI) complexes-[(acac)MoO2(L)O2Mo(acac)]. All the ligands essentially act as bridging tetradentate ligands. The complexes are characterized by analytical, conductivity, IR and NMR (1H and 13C) spectral measurements. © 1990.

引用

页码：1011 / 1015

页数：5