THE KINETICS OF COMPLEX CATALYTIC REACTIONS

被引：64

作者：

FROMENT, GF

机构：

[1] Rijksuniversiteit Gent, Ghent, Belg, Rijksuniversiteit Gent, Ghent, Belg

来源：

CHEMICAL ENGINEERING SCIENCE | 1987年 / 42卷 / 05期

关键词：

CATALYSIS - Reaction Kinetics - MATHEMATICAL MODELS;

D O I：

10.1016/0009-2509(87)80057-X

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

The mathematical and statistical tools for parameter estimation and model discrimination in complex kinetic models are briefly reviewed. Hougen-Watson type rate equations are extended to simultaneous reactions and to situations in which the active site concentration varies through the reactor as a consequence of changes in the gas phase composition. Examples are given of the kinetic modeling of processes based upon complex feedstocks. Lumping of components and reactions, as well as partitioning of the networks are illustrated. The benefit of expressing rates in terms of truly elementary mechanisms is discussed.

引用

页码：1073 / 1087

页数：15

共 42 条

[1]

Amberg, 1961, ADV CHEM SER, V20, P182, DOI 10.1021/ba-1961-0033.ch020

[2]

ARIS R, 1968, ARCH RATION MECH AN, V27, P356

[3] COMPUTER-GENERATION OF REACTION NETWORKS AND CALCULATION OF PRODUCT DISTRIBUTIONS IN THE HYDROISOMERIZATION AND HYDROCRACKING OF PARAFFINS ON PT-CONTAINING BIFUNCTIONAL CATALYSTS [J].