THE FREE-RADICAL POLYMERIZATION OF ACRYLAMIDE INITIATED WITH CERIC SULFATE IN THE PRESENCE OF AMINO-ACIDS

被引：22

作者：

ERBIL, C ^{[1
]}

SOYDAN, AB ^{[1
]}

AROGUZ, AZ ^{[1
]}

SARAC, AS ^{[1
]}

机构：

[1] ISTANBUL UNIV,DEPT CHEM,ISTANBUL,TURKEY

来源：

ANGEWANDTE MAKROMOLEKULARE CHEMIE | 1993年 / 213卷

关键词：

D O I：

10.1002/apmc.1993.052130107

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Polymerization of acrylamide initiated with ceric(IV) ion in the presence of methionine, phenylalanine, serine and aspartic acid was investigated in sulfuric acid solution. Maximum yield was obtained at 70-degrees-C and sulfuric acid concentration of 0.16 mol/l. Both conductometric titration and FT-IR results showed that the resulting polymers contained carboxy end groups. According to these findings and previous studies in this field, a suitable polymerization mechanism was proposed.

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页码：55 / 63

页数：9

相关论文

共 14 条

[1]

AHMED KR, 1978, MAKROMOL CHEM, V179, P1193

[2] COPOLYMER OF KETONIC RESIN-POLYACRYLONITRILE [J].

AKAR, A ;

GALIOGLU, O ;

GOCMEN, A ;

SARAC, AS .

JOURNAL OF APPLIED POLYMER SCIENCE, 1990, 39 (08) :1657-1663

[3] KINETICS OF VINYL POLYMERIZATION INITIATED BY CERIC ION IN AQUEOUS SOLUTION [J].

ANANTHANARAYANAN, VS ;

SANTAPPA, M .

JOURNAL OF APPLIED POLYMER SCIENCE, 1965, 9 (07) :2437-+

[4] THE POLYMERIZATION OF ACRYLAMIDE IN AQUEOUS SOLUTION .2. THE EFFECT OF FERRIC PERCHLORATE ON THE X-RAY AND GAMMA-RAY INITIATED REACTION [J].

COLLINSON, E ;

DAINTON, FS ;

MCNAUGHTON, GS .

TRANSACTIONS OF THE FARADAY SOCIETY, 1957, 53 (04) :489-498

[5] POLYAMINOCARBOXYLIC ACIDS-CE(IV) REDOX SYSTEMS AS AN INITIATOR IN ACRYLAMIDE POLYMERIZATION [J].

ERBIL, C ;

CIN, C ;

SOYDAN, AB ;

SARAC, AS .

JOURNAL OF APPLIED POLYMER SCIENCE, 1993, 47 (09) :1643-1648

[6] METAL-ION OXIDATIVE DECARBOXYLATIONS .13. KINETICS AND MECHANISMS OF THE OXIDATION OF N-BENZYLIMINODIACETIC ACID WITH CERIUM(IV) IN ACIDIC PERCHLORATE AND ACIDIC SULFATE MEDIA [J].

HANNA, SB ;

MOEHLENKAMP, ME .

JOURNAL OF ORGANIC CHEMISTRY, 1983, 48 (06) :826-832

[7]

LALITHA J, 1961, VIGNANA PARISHAD AUS, V4, P139

[8] THE POLYMERIZATION OF ACRYLAMIDE INITIATED BY CERIC NITRATE-3-CHLORO-1-PROPANOL REDOX SYSTEMS [J].

MINO, G ;

KAIZERMAN, S ;

RASMUSSEN, E .

JOURNAL OF POLYMER SCIENCE, 1959, 38 (134) :393-401

[9] A NEW METHOD FOR THE PREPARATION OF GRAFT COPOLYMERS - POLYMERIZATION INITIATED BY CERIC ION REDOX SYSTEMS [J].

MINO, G ;

KAIZERMAN, S .

JOURNAL OF POLYMER SCIENCE, 1958, 31 (122) :242-243

[10] THERMAL INITIATION OF VINYL POLYMERIZATION BY CERIC SOLUTIONS [J].

SALDICK, J .

JOURNAL OF POLYMER SCIENCE, 1956, 19 (91) :73-75