{4-Chloro-N'[(2-oxidonaphthalen-1-yl-kappa O)methylidene]benzohydrazidato- kappa N-2',O]dimethyltin(IV)

被引:1
作者
Cui, Jichun [1 ]
Qiao, Yanling [1 ]
Wang, Fei [1 ]
机构
[1] Liaocheng Univ, Coll Chem & Chem Engn, Liaocheng 252059, Shandong, Peoples R China
关键词
D O I
10.1107/S1600536813031826
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
In the title complex, [Sn(CH3)(2)(C18H11ClN2O2)], the SnIv ion is coordinated by two O atoms and an N atom from a 4-chloro-N'(2-oxidonaphthalen-l-y1)methylidenelbenzohydrazidate ligand and two C atoms from two methyl ligands in a distorted trigonal-bipyramidal geometry [Sn-O = 2.092 (3) and 2.144 (3) angstrom; Sn-N = 2.160 (4) angstrom]. The dihedral angle between the naphthalene ring system and the benzene ring is 8.6 (2)degrees. In the crystal, adjacent molecules are linked by weak C-H-center dot center dot center dot O hydrogen bonds, forming a chain along the b axis direction.
引用
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页码:M688 / +
页数:7
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