SELECTIVE DECOUPLING

Low-power broadband decoupling sequences WALTZ-16 and GARP-1 generate large far-from-resonance frequency modulations which preclude selectivity. The framework developed to construct these broadband sequences is modified to permit selective spin decoupling. Selective-decoupling sequences are created from shaped 90° pulses combined consecutively using WALTZ permutations and supercycle symmetry while shaped 180° pulses are combined in supercycle symmetry to make inversion-based decoupling sequences. Simulations and experiments compare the decoupling bandwidth, frequency selectivity, and quality of near-resonance decoupling for broadband and selective-decoupling sequences. © 1993 Academic Press. All rights reserved.