THE SELF-ASSEMBLY OF A [2] CATENANE

被引：0
|
作者：
BROWN, CL [1 ]
PHILP, D [1 ]
STODDART, JF [1 ]
机构：
[1] UNIV SHEFFIELD, DEPT CHEM, SHEFFIELD S3 7HF, S YORKSHIRE, ENGLAND
来源：
SYNLETT | 1991年 / 07期
关键词：
D O I：
暂无
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The template-directed synthesis of a [2]catenane, in which the interlocking rings are bisparaphenylene-34-crown-10 (BPP34C10) and a cyclobis(paraquat-p-phenylene) tetracationic macrocycle, is reported to occur when 4,4'-bipyridine and 1,4-bis(bromomethyl)benzene are added to a solution of BPP34C10 in dimethylformamide. This remarkable act of self-assembly, which requires the coming together of five molecular components, is rationalised in terms of the mutual recognition properties displayed by the individual parts of a compound undergoing construction in a modular manner.
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页码：459 / 461
页数：3
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