REACTIVITY OF ACYLSILANE PHENYLHYDRAZONES WITH PHOSPHORUS TRICHLORIDE

被引：6

作者：

BARTOLI, G ^{[1
]}

BOSCO, M ^{[1
]}

DALPOZZO, R ^{[1
]}

MARCANTONI, E ^{[1
]}

机构：

[1] DIPARTIMENTO CHIM ORGAN A MANGINI,I-40136 BOLOGNA,ITALY

来源：

TETRAHEDRON LETTERS | 1990年 / 31卷 / 47期

关键词：

D O I：

10.1016/S0040-4039(00)97211-3

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Nitriles are obtained from reaction of acyltrimethylsilane phenylhydrazones with phosphorus trichloride, whereas under the same experimental conditions triphenylsilyl derivatives decompose and t-butyldimethylsilyl derivatives do not react. Evidences of the reaction pathway are reported. © 1990.

引用

页码：6935 / 6936

页数：2

共 12 条

[1] SILICON-INDUCED FRAGMENTATIONS - STEREOSELECTIVE PREPARATION OF (Z,E)-1,4-DIENAMINE AND (Z,Z)-1,4-DIENAMINE DERIVATIVES - SYNTHESIS OF (9Z,12E)-TETRADECADIEN-1-YL ACETATE, PHEROMONE OF VARIOUS LEPIDOPTERA [J].

BAC, NV ;

LANGLOIS, Y .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1982, 104 (26) :7666-7667

[2] REACTION OF KETONE ALKYLHYDRAZONES WITH PHOSPHORUS TRICHLORIDE - A GENERAL MILD ROUTE TO SUBSTITUTED PYRROLES [J].

BACCOLINI, G .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1989, (05) :1053-1056

[3] INDOLIZATION BY PHOSPHORUS TRICHLORIDE OF FUNCTIONALIZED KETONE ARYLHYDRAZONES - SYNTHESIS OF PHARMACOLOGICAL INTERESTING INDOLES [J].

BACCOLINI, G ;

DALPOZZO, R ;

TODESCO, PE .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1988, (04) :971-973

[4] SYNTHESIS OF SILYL- AND GERMYLDIAZOALKANES VIA TOSYLHYDRAZONES [J].

BROOK, AG ;

JONES, PF .

CANADIAN JOURNAL OF CHEMISTRY, 1969, 47 (23) :4353-&

[5] SYNTHESIS OF SILYL AND GERMYL KETONES [J].

BROOK, AG ;

DUFF, JM ;

NONES, PF ;

DAVIS, NR .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1967, 89 (02) :431-&

[6] SYNTHESIS OF ALPHA-SILYL KETONES VIA 1,3-DITHIANES [J].

COREY, EJ ;

SEEBACH, D ;

FREEDMAN, R .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1967, 89 (02) :434-&

[7] PREPARATION OF 2-SUBSTITUTED PYRROLES AND INDOLES BY REGIOSELECTIVE ALKYLATION AND DEPROTECTION OF 1-(2-TRIMETHYLSILYLETHOXYMETHYL)PYRROLE AND 1-(2-TRIMETHYLSILYLETHOXYMETHYL) INDOLE [J].

EDWARDS, MP ;

DOHERTY, AM ;

LEY, SV ;

ORGAN, HM .

TETRAHEDRON, 1986, 42 (13) :3723-3729

[8]

IRITANI K, 1988, TETRAHEDRON LETT, V29, P1789

[9]

KAUFMANN KD, 1968, TETRAHEDRON LETT, P4973

[10] TETRAHYDROFURANS VIA ISOXAZOLINE - A TANDEM 1,3-DIPOLAR CYCLOADDITION ELECTROPHILIC CYCLIZATION SEQUENCE [J].

KURTH, MJ ;

RODRIGUEZ, MJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1987, 109 (24) :7577-7578

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