A RIGOROUS DERIVATION OF THE CHEMICAL MASTER EQUATION

被引：753

作者：

GILLESPIE, DT

机构：

[1] Research Department, Naval Weapons Center, China Lake

来源：

PHYSICA A | 1992年 / 188卷 / 1-3期

关键词：

D O I：

10.1016/0378-4371(92)90283-V

中图分类号：

O4 [物理学];

学科分类号：

0702 ;

摘要：

It is widely believed that the chemical master equation has no rigorous microphysical basis, and hence no a priori claim to validity. This view is challenged here through arguments purporting to show that the chemical master equation is exact for any gas-phase chemical system that is kept well stirred and thermally equilibrated.

引用

页码：404 / 425

页数：22

共 6 条

[1] GENERAL METHOD FOR NUMERICALLY SIMULATING STOCHASTIC TIME EVOLUTION OF COUPLED CHEMICAL-REACTIONS [J].