RATE CONSTANTS FOR REACTIONS OF PEROXYL RADICALS IN FLUID SOLUTIONS

被引：373

作者：

NETA, P

HUIE, RE

ROSS, AB

机构：

[1] Chemical Kinetics Division, National Institute of Standards and Technology, Gaithersburg

[2] Radiation Chemistry Data Center, Radiation Laboratory, University of Notre Dame, Notre Dame

来源：

JOURNAL OF PHYSICAL AND CHEMICAL REFERENCE DATA | 1990年 / 19卷 / 02期

关键词：

alkyl radicals; ALKYL RADICALS; alkylperoxyl radicals; aqueous solution; AQUEOUS SOLUTIONS; chemical kinetics; CHEMICAL REACTION KINETICS; DATA COMPILATION; EXPERIMENTAL DATA; HYDROLYSIS; oxygen; OXYGEN; oxygen radicals; PEROXY RADICALS; peroxyl radicals; photolysis; PHOTOLYSIS; radiolysis; RADIOLYSIS; rate constants; REACTIVITY; SOLUTIONS;

D O I：

10.1063/1.555854

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Absolute rate constants for reactions of alkylperoxyl and substituted alkylperoxyl radicals with inorganic and organic compounds in aqueous and non aqueous fluid solutions have been compiled. The radicals have been generated by radiolysis or photolysis and their rate constants were determined generally by kinetic spectrophotometry or esr. Rate constants are included also for formation of peroxyl radicals by reaction of alkyl radicals with oxygen and for decay of peroxyl radicals by radical radical reactions. © 1990, American Institute of Physics for the National Institute of Standards and Technology. All rights reserved.

引用

页码：413 / 513

页数：101