MOLECULAR TRAINS - THE SELF-ASSEMBLY AND DYNAMIC PROPERTIES OF 2 NEW CATENANES

被引：49
|
作者：
ASHTON, PR
BROWN, CL
CHRYSTAL, EJT
PARRY, KP
PIETRASZKIEWICZ, M
SPENCER, N
STODDART, JF
机构：
[1] DEPT CHEM,SHEFFIELD S3 7HF,ENGLAND
[2] POLISH ACAD SCI,INST PHYS CHEM,PL-01224 WARSAW,POLAND
[3] ICI PLC,AGROCHEM,JEALOTTS HILL RES STN,BRACKNELL RG12 6EY,BERKS,ENGLAND
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1991年 / 30卷 / 08期
关键词：
D O I：
10.1002/anie.199110421
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The tetracationic cyclophane (the ''train'') travels at high speed around the polyether macrocycle (the ''track'') of the [2]catenane 1. The synthesis of the polyether macrocycle in a total yield of > 60% made possible the formation of 1 and of the analogous [3]catenane, in which the two smaller members of the chain are present on diametrically opposite hydroquinone rings according to the H-1 NMR spectrum. All that remains to be done is to introduce signals to direct the train.
引用
收藏
页码：1042 / 1045
页数：4
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