NEW SYNTHESES AND PHYSICAL-PROPERTIES OF PARA-ALKYLCALIX[N]ARENES

被引：47

作者：

SHINKAI, S ^{[1
]}

NAGASAKI, T ^{[1
]}

IWAMOTO, K ^{[1
]}

IKEDA, A ^{[1
]}

HE, GX ^{[1
]}

MATSUDA, T ^{[1
]}

IWAMOTO, M ^{[1
]}

机构：

[1] MIYAZAKI UNIV, FAC ENGN, DEPT IND CHEM, MIYAZAKI 88921, JAPAN

来源：

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 1991年 / 64卷 / 02期

关键词：

D O I：

10.1246/bcsj.64.381

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Calix[n]arenes (n = 4, 6, and 8) bearing long p-alkyl groups (R = hexyl and dodecyl) have been synthesized by ''direct'' acylation of the p-position followed by silane reduction. The method is convenient and the yields are higher than those reported so far. Among them, p-hexanoylcalix[4]arene showed a curious phase transition behavior; with raising the temperature it changed as crystal A-->liquid-->crystal B-->liquid. It was found on the basis of the solid C-13 NMR spectra that this behavior is ascribed to a conformational change from ''cone'' (crystal A) to ''partial cone'' (crystal B).

引用

页码：381 / 386

页数：6

共 19 条

[1] MOLECULAR INCLUSION IN FUNCTIONALIZED MACROCYCLES .6. THE CRYSTAL AND MOLECULAR-STRUCTURES OF THE CALIX[4]ARENE FROM PARA-(1,1,3,3-TETRAMETHYLBUTYL)PHENOL AND ITS 1-1 COMPLEX WITH TOLUENE [J].

ANDREETTI, GD ;

POCHINI, A ;

UNGARO, R .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1983, (11) :1773-1779

[2] CRYSTAL AND MOLECULAR-STRUCTURE OF CYCLO(QUATER[(5-TERT-BUTYL-2-HYDROXY-1,3-PHENYLENE)METHYLENE]) TOLUENE (1-1) CLATHRATE [J].

ANDREETTI, GD ;

UNGARO, R ;

POCHINI, A .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1979, (22) :1005-1007

[3] ON THE CONFORMATIONAL ISOMERS IN TETRA-O-ALKYLCALIX[4]ARENES [J].

ARAKI, K ;

IWAMOTO, K ;

SHINKAI, S ;

MATSUDA, T .

CHEMISTRY LETTERS, 1989, (10) :1747-1750

[4] FRIES REARRANGEMENT IN CALIXARENE ESTERS - A NEW ENTRY FOR THE SYNTHESIS OF PARA-SUBSTITUTED CALIXARENES [J].

ARIMURA, T ;

SHINKAI, S ;

MATSUDA, T ;

HIRATA, Y ;

SATOH, H ;

MANABE, O .

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1988, 61 (10) :3733-3734

[5] PREPARATION OF SERIES OF CALIX[6]ARENES AND CALIX[8]ARENES DERIVED FROM P-N-ALKYLPHENOLS [J].

ASFARI, Z ;

VICENS, J .

TETRAHEDRON LETTERS, 1988, 29 (22) :2659-2660

[6] COMPUTATIONAL STUDY OF THE STRUCTURAL, ENERGETICAL, AND ACID-BASE PROPERTIES OF CALIX[4]ARENES [J].

GROOTENHUIS, PDJ ;

KOLLMAN, PA ;

GROENEN, LC ;

REINHOUDT, DN ;

VANHUMMEL, GJ ;

UGOZZOLI, F ;

ANDREETTI, GD .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1990, 112 (11) :4165-4176

[7] CALIXARENES .13. THE CONFORMATIONAL PROPERTIES OF CALIX[4]ARENES, CALIX[6]ARENES, CALIX[8]ARENES, AND OXACALIXARENES [J].

GUTSCHE, CD ;

BAUER, LJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1985, 107 (21) :6052-6059

[8] CALIXARENES [J].

GUTSCHE, CD .

ACCOUNTS OF CHEMICAL RESEARCH, 1983, 16 (05) :161-170

[9] CALIXARENES .12. THE SYNTHESIS OF FUNCTIONALIZED CALIXARENES [J].

GUTSCHE, CD ;

LIN, LG .

TETRAHEDRON, 1986, 42 (06) :1633-1640

[10] CALIXARENES .14. THE CONFORMATIONAL PROPERTIES OF THE ETHERS AND ESTERS OF THE CALIX[6]ARENES AND THE CALIX[8]ARENES [J].

GUTSCHE, CD ;

BAUER, LJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1985, 107 (21) :6059-6063

← 1 2 →