KINETICS OF PARTIAL OXIDATION OF METHYLACROLEIN TO METHACRYLIC-ACID ON MODIFIED PHOSPHOMOLYBDENUM CATALYST .2. KINETICS OF METHYLACROLEIN OXIDATION

被引：0

作者：

KORCHAK, VN

KUTYREV, MY

STAROVEROVA, IN

机构：

来源：

KINETICS AND CATALYSIS | 1990年 / 31卷 / 06期

关键词：

D O I：

暂无

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The kinetics of oxidation of methylacrolein to methacrylic acid on a phosphomolybdenum catalyst has been studied. A scheme for the process has been proposed and its kinetic parameters have been determined, which satisfactorily account for the experimental results in the temperature range 310-345-degrees-C for methylacrolein and acid concentrations in the initial reaction mixture of 1.4-3% by volume and 2-18% by volume respectively. The kinetics of further oxidation of methacrylic acid have been studied. A mathematical model of the process of methylacrolein oxidation has been developed for an ideal isothermal reaction vessel.

引用

页码：1247 / 1252

页数：6

共 50 条

[1] Kinetics of partial oxidation of methylacrolein to methacrylic acid on modified phosphomolybdenum catalyst. II. Kinetics of methylacrolein oxidation
Korchak, V.N.
Kutyrev, M.Yu.
Staroverova, I.N.
Kinetics and Catalysis (English translation of Kinetika i Kataliz), 1991, 31 (6 pt 2): : 1247 - 1252
[2] KINETICS OF PARTIAL OXIDATION OF METHYLACROLEIN TO METHACRYLIC-ACID ON MODIFIED PHOSPHOMOLYBDENUM CATALYST .1. CATALYST ACTIVATION AND DECOMPOSITION
KORCHAK, VN
KUTYREV, MY
STAROVEROVA, IN
LEMBERANSKII, RA
BABASHEVA, OL
MANUKOVA, LT
KINETICS AND CATALYSIS, 1990, 31 (06) : 1244 - 1247
[3] Cerium-Modified Phosphomolybdenum Heteropoly Acid for Selective Oxidation of Methylacrolein to Methacrylic Acid
Qian, Haitao
Zhang, Guoliang
Li, Jie
Li, Chunshan
Li, Zengxi
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2025, 64 (06) : 3254 - 3263
[4] OXIDATION OF METHYLACROLEIN TO METHACRYLIC-ACID ON PHOSPHOMOLYBDIC ACID, MODIFIED BY ALKALI-METAL IONS AND NH4(+)
STAROVEROVA, IN
KUTYREV, MY
STAKHEEV, AY
KINETICS AND CATALYSIS, 1992, 33 (01) : 101 - 105
[5] MODIFICATION OF PHOSPHOMOLYBDIC ACID AND ITS COMPOUNDS - CATALYSTS FOR THE SELECTIVE OXIDATION OF METHYLACROLEIN TO METHACRYLIC-ACID .2. SYSTEMS MODIFIED BY AMMONIUM, VANADIUM, AND ZINC IONS
STAROVEROVA, IN
ROZENTULLER, BV
KUTYREV, MY
KINETICS AND CATALYSIS, 1986, 27 (03) : 602 - 606
[6] PRODUCTION OF METHACRYLIC-ACID ESTERS BY THE HETEROGENEOUS CATALYTIC-OXIDATION OF ALPHA-METHYLACROLEIN IN THE PRESENCE OF ALCOHOLS
LINDE, VR
KIRYAKOVA, OV
SYURAKSHIN, AV
PETROLEUM CHEMISTRY, 1994, 34 (06) : 513 - 517
[7] NEW CATALYST, BASED ON NICKEL-OXIDE DEPOSITED ON ALUMINA, FOR SELECTIVE OXIDATION OF ISOBUTENE INTO METHYLACROLEIN AND ACETONE .2. REACTION-KINETICS AND MECHANISM
MULLER, A
JUILLET, F
TEICHNER, SJ
BULLETIN DE LA SOCIETE CHIMIQUE DE FRANCE PARTIE I-PHYSICOCHIMIE DES SYSTEMES LIQUIDES ELECTROCHIMIE CATALYSE GENIE CHIMIQUE, 1976, (9-10): : 1361 - 1368
[8] MODIFICATION OF PHOSPHOMOLYBDIC ACID AND ITS COMPOUNDS - CATALYSTS FOR THE SELECTIVE OXIDATION OF METHYLACROLEIN TO METHACRYLIC-ACID .1. MODIFICATION OF THE HETEROPOLY ACID BY ALKALI-METAL IONS
STAROVEROVA, IN
KUTYREV, MY
KHVTISIASHVILI, LG
KINETICS AND CATALYSIS, 1986, 27 (03) : 596 - 602
[9] CATALYTIC-OXIDATION OF ISOBUTENE TO METHACRYLIC-ACID .2. CO-MO-TE-O CATALYST
SAID, G
GERMAIN, JE
BULLETIN DE LA SOCIETE CHIMIQUE DE FRANCE PARTIE I-PHYSICOCHIMIE DES SYSTEMES LIQUIDES ELECTROCHIMIE CATALYSE GENIE CHIMIQUE, 1982, (7-8): : 280 - 283
[10] MODIFICATION OF PHOSPHOMOLYBDIC ACID AND ITS COMPOUNDS - CATALYSTS FOR THE SELECTIVE OXIDATION OF METHYLACROLEIN TO METHACRYLIC ACID. II. SYSTEMS MODIFIED BY AMMONIUM, VANADIUM, AND ZINC IONS.
Staroverova, I.N.
Rozentuller, B.V.
Kutyrev, M.Yu.
Kinetics and Catalysis, 1986, 27 (3 pt 2) : 602 - 606

← 1 2 3 4 5 →