STRUCTURAL EFFECTS IN REACTIONS OF ORGANOPHOSPHORUS COMPOUNDS .I. REACTIONS OF PHOSPHORUS OXYCHLORIDE WITH HINDERED PHENOLS

被引：45

作者：

KOSOLAPOFF, GM

ARPKE, CK

LAMB, RW

REICH, H

机构：

[1] F.J. Seiler Research Laboratory OAR, U.S. Air Force Academy

[2] School of Chemistry, Auburn University, Auburn, AL

来源：

JOURNAL OF THE CHEMICAL SOCIETY C-ORGANIC | 1968年 / 07期

关键词：

D O I：

10.1039/j39680000815

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

2,6-Dialkyl-phenols exhibit little steric hindrance on reaction with phosphoryl chloride unless the alkyl substituent is bulky (i.e. t-butyl). Where bulky substituents are present reaction with phosphoryl chloride occurs only in the presence of Friedel-Crafts type catalysts after either a dealkylation or a rearrangement of the ortho-placed alkyl groups, followed by O-phosphorylation, has occurred.

引用

页码：815 / +

页数：1

共 13 条

[1]

AUTENRIETH W, 1925, BER, V58, P2146

[2]

BOURNEUF M, 1923, B SOC CHIM FR, V33, P1808

[3]

KAMAI G, 1934, ZH OBSHCH KHIM, V4, P192

[4]

KATYSHKINA VV, 1956, ZH OBSHCH KHIM+, V26, P3060

[5]

KOENIGS E, 1934, LIEBIGS ANN CHEM, V509, P138

[6]

MICHAELIS A, 1890, LIEBIGS ANN CHEM, V260, P1

[7]

MICHAELIS A, 1897, LIEBIGS ANN CHEM, V294, P1

[8]

MICHAELIS A, 1896, LIEBIGS ANN CHEM, V293, P193

[9]

PROTOPOPOV IS, 1963, ZH OBSHCH KHIM+, V33, P3050

[10]

PROTOPOPOV IS, 1964, ZH OBSHCH KHIM+, V34, P1446

← 1 2 →