ASYMMETRIC EPOXIDATION CATALYZED BY AN IRON BINAP CAPPED PORPHYRIN

被引：60
作者：
COLLMAN, JP
ZHANG, XM
LEE, VJ
BRAUMAN, JI
机构：
来源：
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1992年 / 22期
关键词：
D O I：
10.1039/c39920001647
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A new chiral metalloporphyrin (iron 'binap capped' porphyrin) has been synthesized and used to catalyse the asymmetric epoxidation of various unsubstituted aromatic olefins; [binap = 2,2'-bis(diphenylphosphino)-1,1'-binaphythyl].
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页码：1647 / 1649
页数：3
相关论文
共 26 条
[1]   SHAPE-SELECTIVE OLEFIN EPOXIDATION CATALYZED BY MANGANESE PICNIC BASKET PORPHYRINS [J].
COLLMAN, JP ;
ZHANG, XM ;
HEMBRE, RT ;
BRAUMAN, JI .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1990, 112 (13) :5356-5357
[2]  
COLONNA S, 1983, SYNTHETIC COMMUN, P105
[3]  
DEMONTELLANO PRO, 1991, J AM CHEM SOC, V113, P3195
[4]   ASYMMETRIC HYDROXYLATION BY A CHIRAL IRON PORPHYRIN [J].
GROVES, JT ;
VISKI, P .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (22) :8537-8538
[5]   ASYMMETRIC HYDROXYLATION, EPOXIDATION, AND SULFOXIDATION CATALYZED BY VAULTED BINAPHTHYL METALLOPORPHYRINS [J].
GROVES, JT ;
VISKI, P .
JOURNAL OF ORGANIC CHEMISTRY, 1990, 55 (11) :3628-3634
[6]   CATALYTIC ASYMMETRIC EPOXIDATIONS WITH CHIRAL IRON PORPHYRINS [J].
GROVES, JT ;
MYERS, RS .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1983, 105 (18) :5791-5796
[7]   CATALYTIC ASYMMETRIC EPOXIDATION OF UNFUNCTIONALIZED ALKENES USING THE 1ST D4-SYMMETRICAL METALLOTETRAPHENYLPORPHYRIN [J].
HALTERMAN, RL ;
JAN, ST .
JOURNAL OF ORGANIC CHEMISTRY, 1991, 56 (18) :5253-5254
[8]   CATALYTIC ASYMMETRIC EPOXIDATION OF UNFUNCTIONALIZED OLEFINS [J].
IRIE, R ;
NODA, K ;
ITO, Y ;
MATSUMOTO, N ;
KATSUKI, T .
TETRAHEDRON LETTERS, 1990, 31 (50) :7345-7348
[9]   CATALYTIC ASYMMETRIC EPOXIDATION OF UNFUNCTIONALIZED OLEFINS USING CHIRAL (SALEN)MANGANESE(III) COMPLEXES [J].
IRIE, R ;
NODA, K ;
ITO, Y ;
MATSUMOTO, N ;
KATSUKI, T .
TETRAHEDRON-ASYMMETRY, 1991, 2 (07) :481-494
[10]   ENANTIOSELECTIVE EPOXIDATION OF UNFUNCTIONALIZED OLEFINS USING CHIRAL (SALEN)MANGANESE(III) COMPLEXES [J].
IRIE, R ;
NODA, K ;
ITO, Y ;
KATSUKI, T .
TETRAHEDRON LETTERS, 1991, 32 (08) :1055-1058
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